Scientific Contributions
Publications (*denotes contribution from undergraduate co-authors, which have been underlined)
Professor
2015
142. A Terminally Bound Nitrido Ligand on Titanium. Maria E. Carroll, Patrick J. Carroll, and D. J. Mindiola, Manuscript in preparation.
141. A New Binding Mode of Dinitrogen to Iron. Keith Searles, Patrick J. Carroll, Jörg Sutter, Karsten Meyer, Kenneth G. Caulton, and Daniel J. Mindiola, Manuscript in preparation.
140. Niobium-Nitrides Derived from Nitrogen Splitting. Keith Searles, Patrick J. Carroll, Chun-Hsing Chen, Maren Pink and D. J. Mindiola. Chem. Commun. advance article online. PDF
139. Synthesis of an Iron(II) Ethyl Complex Accompanied by Formation of an Unusual Dinitrogen-Ligated Iron(I) Hydride. Lindsay J. Hounjet, Debashis Adhikari, Maren Pink, Patrick J. Carroll, and Daniel J. Mindiola. Zeitschrift für Anorganische und Allgemeine Chemie (Special issue on Reactive Nitrogen-Containing Species: Generation, Characterization and Functionalization) 2015, 641, 45-48. PDF
138. Electronic Structure and Reactivity of a Well-Defined Mono-nuclear Complex of Ti(II). Skye Fortier, Timothy A. Jackson, Gayan B. Wijeratne, Chun-Hsing Chen, Patrick J. Caroll, Eva M. Zolnhofer, Karsten Meyer, J. Krzystek, Andrew Ozarowski, Daniel J. Mindiola, and Joshua Telser, Manuscript accepted for publication in Inorg. Chem.
137. Redox and Reactivity of Cyclo-P3 Complexes of Vanadium and the Origin of their P-Chemical Shift. Balazs Pinter, Ba L. Tran, Skye Fortier, Rick Thompson, Gang Wu, Chun-Hsing Chen, Mu-Hyun Baik, and Daniel J. Mindiola, Manuscript in preparation.
136. Addition of Si-H and B-H Bonds and Redox Reactivity Involving Low-Coordinate Nitrido Vanadium Complexes. Ba L. Tran, Rick Thompson, Soumya Ghosh, Chung-Hsing Chen, Maren Pink, Xinfeng Gao, Patrick J. Carroll, Mu-Hyun Baik and Daniel J. Mindiola, Manuscript accepted to Inorg. Chem.
135. β-Hydrogen Abstraction of an Ethyl Group Provides Entry to Stable Titanium and Zirconium Ethylene Complexes. Masahiro Kamitani, Keith Searles, Patrick J. Carroll, and Daniel J. Mindiola, Manuscript accepted to Organometallics (Special Issue honoring Prof. Michael Lappert).
2014
134. A cis-Divacant Mononuclear Iron(IV) Imide. Keith Searles, Skye Fortier, Marat Khusniyarov, Chin-Hsing Chen, Maren Pink, Patrick J. Carroll, Jörg Sutter, Karsten Meyer, Daniel J. Mindiola, and Kenneth G. Caulton, Angew. Chem. Int. Ed. 2014, 53, 14139-14143. PDF
133. Dehydrogenation of Hydrocarbons with Metal-Carbon Multiple Bonds and Trapping of a Titanium(II) Intermediate. Anne Hickey, Marco G. Crestani, Alison R. Fout, Xinfeng Gao, Chun-Hsing Chen, and Daniel J. Mindiola, Dalton Trans. 2014, 43, 9834-9837. PDF
132. A Nitrido Salt Reagent of Titanium. Rick Thompson, Gang Wu, Chun-Hsing Chen, Maren Pink, and Daniel J. Mindiola, J. Am. Chem. Soc. 2014, 13, 8197-8200. PDF
131. Mononuclear Zirconium and Hafnium Methylidenes. Masahiro Kamitani, Balazs Pinter, Chun-Hsing Chen, Maren Pink, and Daniel J. Mindiola, Angew. Chem. Int. Ed. 2014, 53, 10913-10915 (hot paper and selected for front cover of journal). PDF
130. N-N Bond Cleavage in Diazoalkanes with a Titanium Alkylidenes. Jun-ichi Ito, Marco G. Crestani, Brad C. Bailey, Xinfeng Gao, and Daniel J. Mindiola, Polyhedron 2014, 84, 177-181 (Special Issue dedicated to Prof. John Bercaw). PDF
129. A Tantalum Methylidene Complex Supported by a Robust and Sterically Encumbering Aryloxide Ligand. Keith Searles, Balaz Pinter, Chun-Hsing Chen, Daniel J. Mindiola, Organometallics 2014, 33, 4192-4199. PDF
128. Transition Metal Chlorides are Lewis Acids towards Terminal Chloride Attached to Late Transition Metals, Alice K. Hui, Brian J. Cook, Daniel J. Mindiola, and Kenneth G. Caulton, Inorg. Chem. 2014, 53, 3307-3310. PDF
127. Hydrogen Abstraction of a Vinylic Hydrogen to Form Alkynes. Multidimensional and Multinuclear NMR Spectroscoscopic Studies Elucidating Structural Solution Behavior of Alkyne Complexes of Titanium. Anne Hickey, Marco G. Crestani, Balazs Pinter, Xinfeng Gao, and Daniel J. Mindiola, Organometallics 2014, 33, 1157-1173. PDF
126. Mechanistic Understanding of a Silver Pyridylpyrrolide as a Catalyst for 3+2 Cyclization of Nitrile with Diazoester. Jaime A. Flores, Kuntal Pal, Maria E. Carroll, Maren Pink, Jonathan A. Karty, Daniel J. Mindiola, and Kenneth G. Caulton. Organometallics 2013, 33, 1544-1552. PDF
125. Binary Role of an Ylide in Formation of a Terminal Methylidene Complex of Niobium. Keith Searles, Karlijn Keijzer, Chun-Hsing Chen, Mu-Hyun Baik, and Daniel J. Mindiola, Chem. Commun. 2014, 50, 6267-6269. PDF
124. Structural Elucidation of the Illustrous Tebbe Reagent. Rick Thompson, Eiko Nakamaru-Ogiso, Chun-Hsing Chen, Maren Pink, and Daniel J. Mindiola, Organometallics 2014, 33, 429-432. PDF C& E News, vol 92, page 21 (January 5, 2014). website
2013
123. Uranium(III) Complexes with Bulky Aryloxide Ligands Featuring Metal‒Arene Interactions and Their Reactivity Towards Nitrous Oxide. Sebastian M. Franke, Ba L. Tran, Frank W. Heinemann, Wolfgang Hieringer, Daniel J. Mindiola, and Karsten Meyer, Inorg. Chem. 2013, 52, 10552-10558. PDF
122. 3d Early Transition Metal Complexes Supported by a New Sterically Demanding Aryloxide Ligand. Keith Searles, Ba L. Tran, Maren Pink, Chun-Hsing Chen, and Daniel J. Mindiola, Inorg. Chem. 2013, 52, 11126-11135. PDF
Correction for the above manuscript: PDF
121. A Dinuclear Cobalt Complex Featuring Unprecedented Anodic and Cathodic Redox Switches for Single-Molecule Magnet Activity. Skye Fortier, Jennifer J. Le Roy, Chun-Hsing Chen, Veacheslav Vieru, Muralee Murugesu, Liviu F. Chibotaru, Daniel J. Mindiola, and Kenneth G. Caulton, J. Am. Chem. Soc. 2013, 135, 14670-14678. PDF
120. Room Temperature Dehydrogenation of Ethane, Propane, Linear Alkanes C4-C8, and Some Cyclic Alkanes by Titanium-Carbon Multiple Bonds. Marco G. Crestani, Anne K. Hickey, Xinfeng Gao, Balazs Pinter, Vincent N. Cavaliere, Jun-Ichi Ito,Chun-Hsing Chen, and Daniel J. Mindiola, J. Am. Chem. Soc. 2013, 135, 14754-14767. PDF
119. Formation and Reactivity of the Terminal Vanadium Nitride Functionality. Ba L. Tran, J. Krzystek, Andrew Ozarowski, Chung-Hsing Chen, Maren Pink, Jonathan A. Karty, Joshua Telser, Karsten Meyer and Daniel J. Mindiola, Eur. J. Inorg. Chem. (Special issue on small molecule activation) 2013, 3916-3929. PDF
118. Büchner Reactions Catalyzed by a Silver(I) Pyridylpyrrolide: Understanding Arene C=C Insertion Selectivity. Komine Nobuyuki, Jaime A. Flores, Kuntal Pal, Kenneth G. Caulton, and Daniel J. Mindiola, Organometallics 2013, 32, 3185-3191. PDF
117. Understanding Competitive Pathways Involving the Dehydroalkoxylation and Dehydrogenation of Ethers with Ti-C Multiple Bonds. Marco G. Crestani, Balazs Pinter, Andras Olasz, Brad C. Bailey, Skye Fortier, Xinfeng Gao, Chun-Hsing Chen, Mu-Hyun Baik, and Daniel J. Mindiola, Chem. Sci. 2013,4, 2543-2550. PDF
116. A Four-Coordinate Thionitrosyl Complex of Vanadium. Rick Thompson, Ba L. Tran, Soumya Ghosh, Xinfeng Gao, Chun-Hsing Chen, Mu-Hyun Baik, and Daniel J. Mindiola, Chem. Commun. 2013, 49, 2768-2770. PDF
115. 2,2’-Pyridylpyrrolide Ligand Redistribution Following Reduction. Keith Searles, Atanu K. Das, René W. Buell, Maren Pink, Chun-Hsing Chen, Kuntal Pal, David Gene Morgan, Daniel J. Mindiola, and Kenneth G. Caulton, Inorg. Chem. 2013, 52, 5611-5619. PDF
114. Understanding Intermolecular C-F Bond Activation by a Transient Titanium Neopentylidyne. Experimental and Theoretical Studies Distinguishing Competitive Pathways such as 1,2-CF Bond Addition from [2+2]-Cycloaddition/β-Flouride Elimination. Hongjun Fan, Alison R. Fout, Brad C. Bailey, Maren Pink, Mu-Hyun Baik, and Daniel J. Mindiola, Dalton Trans. Special Issue in Organometallic Chemistry 2012, 42, 4163-4174. PDF
2012
113. Vanadocene de Novo: Spectroscopic and Computational Analysis of Bis(η5-cyclopentadienyl)vanadium(II). Joshua Telser, Timothy Jackson, Gayan Wijeratne, Daniel J.Mindiola, Benjamin F. Wicker, Jurek Krzystek, Andrew Ozarowski, Organometallics 2012, 31, 8265–8274. PDF
112. Probing the redox non-innocence of dinuclear, three-coordinate Co(II) nindigo complexes: not simply β-diketiminate variants. Skye Fortier, Octavio González-del Moral, Chun-Hsing Chen, Maren Pink, Jennifer J. Le Roy, Muralee Murugesu, Daniel J. Mindiola, and Kenneth G. Caulton, Chem. Commun. 2012, 48, 11082-11084. PDF
111. An iridium-pyridylpyrrolide complex exhibiting reversible binding of H2. Keith Searles, Maren Pink, Kenneth G. Caulton, and Daniel J. Mindiola, Dalton Trans. 2012, 41, 9619-9622. PDF
Dalton Trans. New Talent Issue: American. Daniel J. Mindiola, John Arnold, Theo Agapie, Jennifer Love and Mircea Dincă, Dalton Trans.(Editorial) 2012, 41, 7781. PDF
110.* A Planar Three-Coordinate Vanadium(II) Complex and Terminal Vanadium Nitrides from N2. A Kinetic or Thermodynamic Impediment? Ba L. Tran, Balazs Pinter, Adam J. Nichols, Chun-Hsing Chen, J. Krzystek, Andrew Ozarowski, Joshua Telser, Mu-Hyun Baik, Karsten Meyer, and Daniel J. Mindiola, J. Am. Chem. Soc. 2012, 134, 13035-13045. PDF
109. A Mononuclear Fe(III) Single Molecule Magnet with a 3/2 ↔ 5/2 Spin Crossover. Susanne Mossin, Ba L. Tran, Debashis Adhikari, Maren Pink, Frank W. Heinemann, Jörg Sutter, Robert K. Szilagyi, Karsten Meyer, and Daniel J. Mindiola, J. Am. Chem. Soc. 2012, 134, 13651-13661. PDF
108. Evidence for the Existence of Terminal Scandium Imidos. Mechanistic Studies Involving Sc=N Bond Formation and C-H Activation Reactions. Benjamin F. Wicker, Hongjun Fan, Anne K. Hickey, Marco G. Crestani, Jennifer Scott, Maren Pink, Mu-Hyun Baik, and Daniel J. Mindiola, J. Am. Chem. Soc. 2012, 134, 20081-20096. PDF
107. Homogeneous Organometallic Chemistry of Methane. Vincent N. Cavaliere, Benjamin F. Wicker, and Daniel J. Mindiola, Adv. Organomet. Chem. 2012, 60, 1-47. website
106. Methane: A New Frontier in Organometallic Chemistry. Vincent N. Cavaliere and Daniel J. Mindiola, Chem. Sci. 2012,3, 3356-3365. PDF
105.* A Four Coordinate Parent Imide Via a Titanium Nitridyl. Ba L. Tran, Marlena Washington, Danielle A. Henckel, Xinfeng Gao, Maren Pink, and Daniel J. Mindiola, Chem. Commun. 2012, 48, 1529-1531 (Invited contribution to the "New Talent" special issue). PDF
104. Silver(I)-Catalyzed Insertion of Carbene into Alkane C-H Bonds and the Origin of the Special Challenge of Methane Activation Using DFT as a Mechanistic Probe. Jaime A. Flores, Komine Nobuyuki, Kuntal Pal, Balazs Pinter, Maren Pink, Chun-Hsing Chen, Kenneth G. Caulton and Daniel J. Mindiola, ACS Catalysis 2012, 2, 2066-2078. PDF
2011
103. Isocyanide Insertion and Cyclization Reactions to Form Indolines Using Pincer-Type Complexes of Scandium. Benjamin F. Wicker, Maren Pink, and Daniel J. Mindiola, Dalton Trans. 2011, 40, 9020-9025 (Special themed issue: Pincers and other hemilabile ligands). PDF
102. 1,2-CF Bond Activation of Perfluoroarenes and Alkylidene Isomers of Titanium. DFT Analysis of the C-F Bond Activation Pathway and Rotation of the Titanium Alkylidene Moiety. José G. Andino, Hongjun Fan, Alison R. Fout, Brad C. Bailey, Mu-Hyun Baik, and Daniel J. Mindiola, J. Organomet. Chem. 2011, 696, 4138-4146 (special issue " Small Molecule Activation and Catalysis Invoking Metal-Carbon Multiple Bonds", which is dedicated to Professor Ken Caulton on the occasion of his 70th birthday). PDF
Foreword to special issue on metal–carbon multiple bonds and the activation of small molecules: J. Organomet. Chem. 2011, 696, 3909. PDF
Biographical Sketch for Kenneth Caulton: J. Organomet. Chem. 2011, 696, 3910. PDF
101. Room Temperature Dehydrogenation of Ethane to Ethylene. Vincent N. Cavaliere, Marco G. Crestani, Balazs Pinter, Chun-Hsing Chen, Maren Pink, Mu-Hyun Baik, and Daniel J. Mindiola, J. Am. Chem. Soc. 2011, 133, 10700-10703. PDF C& E News, vol 89, page 26 (July 4, 2011). website
Author Profile: Daniel J. Mindiola, Angew. Chem. Int. Ed. 2011, 50, 4046. PDF
100. Reactivity Studies of a Pseudo Three-Coordinate Vanadium(II) Complex: Synthesis of Terminal Oxo and Sulfido Complexes of Vanadium(IV) and S-S and Se-Se Reductive Bond Cleavage Reactions. Ba L. Tran, Chun-Hsing Chen, and Daniel J. Mindiola, Inorg. Chim. Acta (Special Issue in Honor of Prof. Robert Bergman), 2011, 369, 215-222. PDF
99. Methane Activation and Exchange by Titanium-Carbon Multiple Bonds. Jaime A. Flores, Vincent N. Cavaliere, Dominik Buck, George Chen, Marco G. Crestani, Balazs Pinter, Mu-Hyun Baik, and Daniel J. Mindiola, Chem. Sci. 2011, 2, 1457-1462 (Front Cover of issue). PDF Highlighted by the RSC Chemistry World (June 2, 2011). website
98. Atom Economical Route to Substituted Pyridines via Scandium Imido. Benjamin F. Wicker, Jennifer Scott, Alison R. Fout, Maren Pink, and Daniel J. Mindiola, Organometallics 2011, 30, 2453-2456. PDF
97. Carbenes vs. Alkylidenes.Spot the Difference. Daniel J. Mindiola and Jennifer Scott, Nature Chem. 2011, 3, 15-17 (Invited News and Views). PDF
96. Understanding a Reactive and Easy-to-Prepare Titanium Carboamination Catalyst. Falguni Basuli, Benjamin Wicker, John C. Huffman, and Daniel J. Mindiola, J. Organomet. Chem. 2011, 696, 235-243. Invited Article for the thematic Issue Entitled "Catalytic Addition of E-H Bonds". PDF
Associate Professor
2010
95.* Reactivity Studies of a Masked Three-Coordinate Vanadium(II) Complex. Ba L. Tran, Madhavi Singhal, Hyunsoo Park, Oanh P. Lam, Maren Pink, J. Krzystek, Andrew Ozarowski, Joshua Telser, Karsten Meyer, and Daniel J. Mindiola, Angew. Chem. Int. Ed. 2010, 49, 9871-9875. PDF
94. Phosphinidene Complexes of Scandium. Powerful PAr Group-Transfer Vehicles to Organic and Inorganic Substrates. Benjamin F. Wicker, Jennifer Scott, José G. Andino, Xinfeng Gao, Maren Pink, and Daniel J. Mindiola J. Am. Chem. Soc. 2010, 132, 3691-3693. PDF
93. Low-Coordinate and Neutral Nitrido Complexes of Vanadium. Ba L. Tran, Maren Pink, Xinfeng Gao, Hyunsoo Park, and Daniel J. Mindiola, J. Am. Chem. Soc. 2010, 132, 1458-1459. PDF
92. Synthetic and Mechanistic Studies of Ring-Opening and Denitrogenation of Pyridine and Picolines. Alison R. Fout, Brad C. Bailey, Dominik Buck, Hongjun Fan, John C. Huffman, Mu-Hyun Baik, and Daniel J. Mindiola, (Prof. Dietmar Seyferth Festschrift) Organometallics 2010, 29, 5409-5422. PDF
91. Intermolecular C-H Bond Activation of Benzene and Pyridines by a Vanadium(III) Alkylidene Including a Stepwise Conversion of Benzene to a Vanadium-Benzyne Complex. José G. Andino, Uriah J. Kilgore, Andrew Ozarowski, J. Krzystek, Joshua Telser, Maren Pink, Mu-Hyun Baik, and Daniel J. Mindiola, Chem. Sci. 2010, 1, 351-356. PDF
90. Cobalt 2,2,6,6-tetramethyl-3,5-bis-(2,6-diisopropylphenylimido)heptyl chloride (L(tBu,iPr2)CoCl). Keying Y. Ding, Thomas R. Dugan, Patrick L. Holland, Debashis Adhikari, Daniel J. Mindiola. Edited by Thomas B. Rauchfuss. Inorganic Synthess, 2010, 35, 43-45. PDF
89. Iron 2,2,6,6-tetramethyl-3,5-bis-(2,6-diisopropylphenylimido)heptyl chloride (LFeCl)-Fe-tBu,iPr2). Karen P. Chiang, Patrick L. Holland, Debashis Adhikari, Daniel J. Mindiola. Edited by Thomas B. Rauchfuss. Inorganic Syntheses, 2010, 35, 41-43. PDF
88. Iron 2,4-bis-(2,6-diisopropylphenylimido)pentyl chloride (L(Me,iPr2)FeCl). Bryan D. Stubbert, Patrick L. Holland, Debashis Adhikari, Daniel J. Mindiola. Edited by Thomas B. Rauchfuss. Inorganic Syntheses, 2010, 35, 38-41. PDF
87. Scandium Trichloride Tris(Tetrahydrofuran) and beta-diketiminate-supported scandium chloride complexes. Paul G. Hayes, Warren E. Piers, Debashis Adhikari, and Daniel J. Mindiola. Edited by Thomas B. Rauchfuss. Inorganic Syntheses, 2010, 35, 20-24. PDF
86. beta-Diketiminate precursors (LH)-H-tBu,iPr2, and (LLi)-Li-tBu,iPr2(THF) (L-tBu, Li-iPr2 = 2,2,6,6-tetramethyl-3,5-bis-(2,6-diisopropylphenylimido)heptyl. Ryan E. Cowley, Karen P. Chiang, Patrick L. Holland, Debashis Adhikari, Francisco J. Zuno-Cruz, Gloria S. Cabrera, and Daniel J. Mindiola. Edited by Thomas B. Rauchfuss. Inorganic Syntheses, 2010, 35, 13-19. PDF
85. beta-Diketiminate precursors (LH)-H-Me,iPr2, [L-Me,Li-iPr2]x, and [(LK)-K-tBu,iPr2]x (L-Me,L-iPr2=2,4-bis-(2,6-diisopropylphenylimidi)pentyl;; L-tBu,L-tPr2 = 2,2,6,6-tetramethyl-3,5-bis-(2,6-diisopropylphenylimido)heptyl. Debashis Adhikari, Ba L. Tran, Francisco J. Zuno-Cruz, Gloria S. Cabrera, Daniel J. Mindiola, Karen P. Chiang, Ryan E. Cowley, Thomas R. Dugan, and Patrick L. Holland. Edited by Thomas B. Rauchfuss. Inorganic Syntheses, 2010, 35, 8-13. PDF
84. Complexes of bulky beta-diketiminate ligands. D. J. Mindiola, Patrick L. Holland, and Timothy H. Warren. Edited by Thomas B. Rauchfuss. Inorganic Syntheses, 2010, 35, 1-4. PDF
2009
83. Facile Entry to 3d Late Transition Metal Boryl Complexes, Invited manuscript for the Theme Issue: New Talent; Inspiration for the Future. Ba L. Tran, Debashis Adhikari, Hongjun Fan, Maren Pink, and Daniel J. Mindiola Dalton Trans. 2009, 39, 358-360. PDF
82. Nacnac...Are You Still There? The Evolution of β-Diketiminate Complexes of Nickel. Daniel J. Mindiola, Angew. Chem. Int. Ed. (Invited "Highlights" article), 2009, 48, 6198-6200. PDF
81. Phosphinidene Group-Transfer with a Phospha-Wittig Reagent: A New Entry to Transition Metal Phosphorus Multiple Bonds. Uriah J. Kilgore, Hongjun Fan, Maren Pink, Eugenijus Urnezius, John D. Protasiewicz and Daniel J. Mindiola, Chem. Commun. 2009, 4521-4523. PDF
80. A Tribute to Frederick Nye Tebbe. Lewis Acid Stabilized Alkylidynes, Alkylidenes, and Imides of 3d Early Transition Metals, Jennifer Scott and Daniel J. Mindiola, Dalton Trans. (Invited "Perspective" article and front cover of issue), 2009, 8463-8472. PDF
79. Zwitterionic and Cationic Titanium and Vanadium Complexes Having Terminal M-C Multiply Bonded Ligands. The Role of the β-Diketiminate Framework in Formation of Charge Separated Species. Debashis Adhikari, Falguni Basuli, Justin H. Orlando, Alison R. Fout, John C. Huffman, and Daniel J. Mindiola, Organometallics 2009, 28, 4115-4125. PDF
78. Catalytic Hydrosilylation of the Carbonyl Functionality via a Transient Nickel Hydride Complex. Ba L. Tran, Maren Pink, Daniel J. Mindiola, Organometallics 2009, 28, 2234-2243. PDF
77. Tellus in, Tellus out: The Chemistry of the Vanadium Bis(telluride) Functionality. Uriah J. Kilgore, Jonathan A. Karty, Maren Pink, Xinfeng Gao, and Daniel J. Mindiola, Angew. Chem. Int. Ed. 2009, 48, 2394-2397. PDF
76. Mild Protocol to Prepare Stable Nickel Complexes Having Primary and Secondary Silyl Ligands. Debashis Adhikari, Maren Pink, and Daniel J. Mindiola, Organometallics 2009, 28, 2072-2077. PDF
75.* A Transient V(III) Neopentylidene Complex. Redox Chemistry and Reactivity of the V=CHtBu Functionality. Uriah J. Kilgore, Caitlin A. Sengelaub, Hongjun Fan, John Tomaszewski, Maren Pink, Jonathan A. Karty, Mu-Hyun Baik, and Daniel J. Mindiola, Organometallics 2009, 28, 843-852. PDF
74.* Dehydrofluorination of Fluorohydrocarbons by Titanium Alkylidynes via Sequential C-H/C-F Bond Activation Reactions. A Synthetic, Structural, and Mechanistic Study of 1,2-CH Bond Addition and β-Fluoride Elimination. Alison R. Fout, Jennifer Scott, Deanna L. Miller, Brad C. Bailey, John C. Huffman, Maren Pink, and Daniel J. Mindiola, Organometallics 2009, 28, 331-347. PDF
2008
73. Lewis Acid Stabilized Methylidene and Oxoscandium Complexes. Jennifer Scott, Hongjun Fan, Benjamin F. Wicker, Alison R. Fout, Mu-Hyun Baik, and Daniel J. Mindiola, J. Am. Chem. Soc. 2008, 130, 14438-14439. PDF
72.* Understanding and Predicting Distorted T- vs. Y-Geometries for Neutral Chromous Complexes Supported by a Sterically Encumbering β-Diketiminate Ligand. Hongjun Fan, Debashis Adhikari, Anas A. Saleh, Rodney L. Clark, Francisco J. Zuno-Cruz, Gloria Sanchez Cabrera, John C. Huffman, Maren Pink, Daniel J. Mindiola, and Mu-Hyun Baik, J. Am. Chem. Soc. 2008, 130, 17351-17361. PDF
71. Evidence for the Existence of a Terminal Imidoscandium Compound. Intermolecular C-H Activation and Complexation Reactions with the Transient Sc=NAr Ligand. Jennifer Scott, Falguni Basuli, Alison R. Fout, John C. Huffman, and Daniel J. Mindiola, Angew. Chem. Int. 2008, 47, 8502-8505. PDF
70. Carboamination Reactions Using Titanium Pre-catalysts. A Catalytic Prospect to Preparing Conjugated C-N/C-C Frameworks. Daniel J. Mindiola, Comments on Inorg. Chem., Invited Article. 2008, 29, 73-92. website
69. P=N Bond Formation Via Incomplete N-Atom Transfer from a Ferrous Amide Precursor. Debashis Adhikari, Falguni Basuli, Hongjun Fan, John C. Huffman, and Daniel J. Mindiola, Inorg. Chem. 2008, 47, 4439-4441. PDF
68. Early-Transition Metal Hydrazidos: Masked Metallanitrenes from N-N Bond Scission. Daniel J. Mindiola, Angew. Chem. Int. Ed. (Invited "Highlights" article) 2008, 47, 1557-1559. PDF
67. Structural, Spectroscopic and Theoretical Elucidation of a Redox Active Pincer-Type Ancillary Applied in Catalysis. Debashis Adhikari, Susanne Mossin, Falguni Basuli, John C. Huffman, Robert K. Szilagyi, Karsten Meyer, and Daniel J. Mindiola, J. Am. Chem. Soc. 2008, 130, 3676-3682. PDF
66.* A Transient VIII Alkylidene Complex. Oxidation Chemistry Including the Activation of N2 to Afford a Highly Porous Honeycomb-Like Arrangement. Uriah J. Kilgore, Caitlin A. Sengelaub, Maren Pink, Alison R. Fout, and Daniel J. Mindiola, Angew. Chem. Int. 2008, 47, 3769-3772. PDF
65. A Dinuclear Ni(I) System Having a Diradical Ni2N2 Diamond Core Resting State. Synthetic, Structural, Spectroscopic Elucidation, and Reductive Bond Splitting Reactions. Debashis Adhikari, Susanne Mossin, Falguni Basuli, Benjamin R. Dible, Mircea Chipara, Hongjun Fan, John C. Huffman, Mu-Hyun Baik, Karsten Meyer, and Daniel J. Mindiola, Inorg. Chem. 2008, 47, 10479-10490. PDF
Assistant Professor
2007
64. Structural Elucidation of a Nickel Boryl Complex. A Recyclable Borylation Ni(II) Reagent of Bromobenzene. Debashis Adhikari, John C. Huffman, and Daniel J. Mindiola, Chem. Commun. 2007, 4489-4491. PDF
63. An Alkylidyne Analogue of Tebbe’s Reagent. Trapping Reactions of a Titanium Neopentylidyne by Incomplete and Complete 1,2-Additions. Brad C. Bailey, Alison R. Fout, Hongjun Fan, John Tomaszewski, John C. Huffman, and Daniel J. Mindiola, Angew. Chem. Int. Ed. 2007, 46, 8246-8249. PDF
62. Cyclic Homogeneous Denitrogenation of N-Heterocycles Applying a Titanium Reagent. Alison R. Fout, Brad C. Bailey, John Tomaszewski, and Daniel J. Mindiola, J. Am. Chem. Soc. 2007, 129, 12640-12641. PDF. Editors' choice in Science Magazine PDF
61. Niobium Bis-Alkylidene Complexes Prepared by a Multi-Electron Redox Process. Uriah J. Kilgore, John Tomaszewski, Hongjun Fan, John C. Huffman, and Daniel J. Mindiola, Organometallics 2007, 26, 6132-6138. PDF
60. The Progression of Synthetic Strategies to Assemble Titanium Complexes Bearing the Terminal Imide Group. Alison R. Fout, Uriah J. Kilgore, and Daniel J. Mindiola, Invited Concepts Article, Chem. Eur. J. 2007, 13, 9428-9440. PDF
59. Addition of Ammonia, Water, and Dihydrogen Across a Single Pd-Pd Bond. Claudia M. Fafard, Debashis Adhikari, Bruce M. Foxman, Daniel J. Mindiola, and Oleg. V. Ozerov, J. Am. Chem. Soc. 2007, 129, 10318-10319. PDF
58. Intermolecular C-H Bond Activation Reactions Promoted by Transient Titanium Alkylidynes. Synthesis, Reactivity, Kinetic, and Theoretical Studies of the Ti≡C Linkage. Brad C. Bailey, Hongjun Fan, John C. Huffman, Mu-Hyun Baik, and Daniel J. Mindiola, J. Am. Chem. Soc. 2007, 129, 8781-8793. PDF
57.* Silver(I) and Thallium(I) Complexes of a PNP Ligand and Their Utility as PNP Transfer Reagents. Jessica C. DeMott, Falguni Basuli, Uriah J. Kilgore, Bruce M. Foxman, John C. Huffman, Oleg V. Ozerov, and Daniel J. Mindiola, Inorg. Chem. 2007, 46, 6271-6276. PDF
56. Snapshots of an Alkylidyne for Nitride Triple Bond Metathesis. Brad C. Bailey, Alison R. Fout, Hongjun Fan, John C. Huffman, J. Brannon Gary, Marc J. A. Johnson, and Daniel J. Mindiola, J. Am. Chem. Soc. 2007, 129, 2234-2235. PDF
55. Intermolecular Activation of C-X (X = H, O, F) Bonds by a Ti≡CtBu Linkage. Brad C. Bailey, John C. Huffman, and Daniel J. Mindiola, J. Am. Chem. Soc. 2007, 129, 5302-5303. PDF
54. Organometallic Consequences of a Redox Reaction. Terminal Trimethylsilylmethylidene Titanium Complexes Prepared by a One-Electron Oxidation Step. Falguni Basuli, Debashis Adhikari, John C. Huffman, and Daniel J. Mindiola, Invited paper for the volume entitled 'One-Electron Reactivity in Organometallic Chemistry'. J. Organomet. Chem. 2007, 692, 3115-3120. Manuscript selected for front art cover. PDF
53. Reductive Cleavage on the NCCCN β-Diketiminate Backbone. A Direct Approach to Azabutadienyl and Alkylidene-Anilide Scaffolds. Invited paper for the issue Inorganic Chemistry - The Next Generation. F. Basuli, J. C. Huffman, D. J. Mindiola, Inorg. Chim. Acta. 2007, 360, 246-254. PDF
2006
52. Activation of Atmospheric Nitrogen and Azobenzene N=N Bond Cleavage by a Transient Nb(III) Complex. Uriah J. Kilgore, Xiaofang Yang, John C. Huffman, and Daniel J. Mindiola, Inorg. Chem. 2006, 45, 10712-10721. PDF
Addition for the above manuscript: PDF
51. Neutral and Zwitterionic Low-Coordinate Titanium Complexes Bearing the Terminal Phosphinidene Functionality. Structural, Spectroscopic, Theoretical, and Catalytic Studies Addressing the Ti-P Multiple Bond. Guangyu Zhao, Falguni Basuli, Uriah J. Kilgore, Hongjun Fan, Halikhedkar Aneetha, John C. Huffman, Gang Wu, and Daniel J. Mindiola, J. Am. Chem. Soc. 2006, 128, 13575-13585. PDF
50. Oxidatively-Induced α-Hydrogen Abstraction. A Mild Protocol to Generate Terminal Titanium Alkylidenes Containing a β-Hydrogen. Brad C. Bailey, Falguni Basuli, John C. Huffman, and Daniel J. Mindiola, Organometallics 2006, 25, 3963-3968. PDF
49. Oxidatively Induced Abstraction Reactions. A Synthetic Approach to Low-Coordinate, Reactive, Early-Transition Metal Complexes Containing Metal-Ligand Multiple Bonds. Daniel J. Mindiola, Invited Microreview, Acc. Chem. Res. 2006, 39, 813-821. PDF
48. What a Difference One Electron Makes! Generating Low-Coordinate Ti-C and V-C Multiply Bonded Frameworks Through One-Electron Oxidatively-Induced α-Hydrogen Abstractions. Daniel J. Mindiola, Brad C. Bailey, and Falguni Basuli, Invited Microreview, Eur. J. Inorg. Chem. 2006, 3135-3146. PDF
47. Room Temperature Ring-Opening Metathesis of Pyridines by a Transient Ti≡C Linkage. Brad C. Bailey, Hongjun Fan, John C. Huffman, Mu-Hyun Baik, and Daniel J. Mindiola, J. Am. Chem. Soc. 2006, 128, 6798-6799. PDF
Correction for the above manuscript: PDF
46. Terminal Titanium(IV) (Trimethylsilyl)imides Prepared by Oxidatively Induced Trimethylsilyl Abstraction. Brad C. Bailey, Falguni Basuli, John C. Huffman, and Daniel J. Mindiola, Organometallics 2006, 25, 2725-2728. PDF
45. Ti(NMe2)4 and [HNMe2Ph][B(C6F5)4]: A Convenient Blend for Effective Catalytic Carboamination of Alkynes. H. Aneetha, F. Basuli, J. Bollinger, J. C. Huffman, and D. J. Mindiola, Organometallics 2006, 25, 2402-2404. PDF
44. Tl(I), Fe(II) and Co(II) Complexes Supported by a Monoanionic N,N,N'-Heteroscorpionate Ligand Bis(3,5-di-tertbutylpyrazol-1-yl)-1-CH2NAr, Ar = 2,6-iPr2C6H3). D. Adhikari, G. Zhao, F. Basuli, J. Tomaszewski, J. C. Huffman, D. J. Mindiola, Inorg. Chem. 2006, 45, 1604-1610. PDF
43. A Co2N2 Diamond Core Resting State of Cobalt(I): A Three-Coordinate Co(I) Synthon Invoking an Unusual Pincer-Type Rearrangement. A. R. Fout, F. Basuli, H. Fan, J. Tomaszewski, J. C. Huffman, M.-H. Baik, D. J. Mindiola, Angew. Chem. Int. Ed. 2006, 45, 3291-3295. PDF
42. Aryl Isocyanate, Carbodiimide, and Isocyanide Derived Prepared from Carbon Dioxide. A Metathetical Group-Transfer Tale Involving a Titanium-Imide Zwitterion. U. J. Kilgore, F. Basuli, J. C. Huffman, D. J. Mindiola. Inorg. Chem. 2006, 45, 487-489. PDF
2005
41. A Fluorobenzene Adduct of Ti(IV), and Catalytic Carboamination to Prepare α,β-Unstaturated Imines and Triaryl Substituted Quinolines. F. Basuli, H. Annetha, J. C. Huffman, D. J. Mindiola, J. Am. Chem. Soc. 2005, 127, 17992-17993. PDF
40.* Titanium Complexes Supported by a Sterically Encumbering N-Anchored Tris-Aryl Phenoxide Ligand. S. A. Cortes, M. A. Muñoz Hernández, I. Castro-Rodriguez, K. Meyer, A. R. Fout, D. A. Miller, J. C. Huffman, D. J. Mindiola, Inorg. Chem. Commun. 2005, 8, 902-906. PDF
39. Intermolecular C-H Bond Activation Promoted by a Titanium Alkylidyne. B. C. Bailey, H. Fan, E. W. Baum, J. C. Huffman, M.-H. Baik, D. J. Mindiola, J. Am. Chem. Soc. 2005, 127, 16016-16017. PDF
38.* Latent Low-Coordinate Titanium Imides Supported by a Sterically Encumbering Beta-Diketiminate Ligand. F. Basuli, R. L. Clark, B. C. Bailey, D. Brown, J. C. Huffman, D. J. Mindiola, Chem. Commun. 2005, 2250-2252. PDF
37. Remarkably Stable Titanium Complexes Having Terminal Alkylidene, Phosphinidene, and Imide Functionalities. B. C. Bailey, J. C. Huffman, D. J. Mindiola, W. Weng, O. V. Ozerov, Organometallics 2005, 24, 1390-1393. PDF
36. Intramolecular C-H Activation Reactions Derived From a Terminal Titanium Neopentylidene Functionality. Redox Controlled 1,2-Addition and α-Hydrogen Abstraction Reactions. F. Basuli, B. C. Bailey, J. C. Huffman, D. J. Mindiola, Organometallics 2005, 24, 3321-3334. PDF
35. Four-Coordinate Titanium Alkylidene Complexes: Synthesis, Reactivity, and Kinetic Studies Involving the Terminal Neopentylidene Functionality. F. Basuli, B. C. Bailey, L. A. Watson, J. Tomaszewski, J. C. Huffman, D. J. Mindiola, Organometallics 2005, 24, 1886-1906. PDF
Addition/Correction for the above manuscript: PDF
2004
34.* Terminal Zirconium Imides Prepared by Reductive C-N Bond Cleavage. F. Basuli, U. J. Kilgore, J. Tomaszewski, D. Brown, J. C. Huffman, D. J. Mindiola, Organometallics 2004, 23, 6166-6175. PDF
33. Four-Coordinate Vanadium-Neopentylidyne Complexes and Intramolecular Wittig Reactions to Generate Azametallacyclohexatrienes. F. Basuli, B. C. Bailey, D. Brown, J. Tomaszewski, J. C. Huffman, M.-H. Baik, D. J. Mindiola, J. Am. Chem. Soc. 2004, 126, 10506-10507. PDF
32. Terminal and Four-Coordinate Vanadium(IV) Phosphinidene Complexes. A Pseudo Jahn-Teller Effect of Second Order Stabilizing the V-P Multiple Bond. F. Basuli, B. C. Bailey, J. C. Huffman, Mu-H. Baik, D. J. Mindiola, J. Am. Chem. Soc. 2004, 126, 1924-1925. PDF
31.* Cationic and Neutral Four-Coordinate Alkylidene Complexes of Vanadium(IV) Containing Short V=C Bonds, F. Basuli, U. J. Kilgore, X. Hu, K. Meyer, M. Pink, J. C. Huffman, D. J. Mindiola, Angew. Chem. Int. Ed. 2004, 43, 3156-3158. PDF
2003
30. Phosphaazaallene and Phosphinylimide Complexes Stemming From a Terminal and Four-Coordinate Titanium Phosphinidene, F. Basuli, L. A. Watson, J. C. Huffman, D. J. Mindiola, Dalton Trans. 2003, 4228-4230. PDF
29. Reactivity at the β-Dketiminate Ligand Nacnac- on Ti(IV) (Nacnac- = [Ar]N(CH3)CHC(CH3)N[Ar], Ar = 2,6-[CH(CH3)2]2C6H3. Diimine-alkoxo and Bis-Anilido Ligands Stemming from the Nacnac- Skeleton, F. Basuli, J. C. Huffman, D. J. Mindiola, Inorg. Chem. 2003, 42, 8003-8010. PDF
28. Carbon-Oxygen Bond Cleavage Promoted by a Scandium-Hydride Complex, F. Basuli, J. Tomaszewski, J. C. Huffman, D. J. Mindiola, Organometallics 2003, 22, 4705-4714. PDF
27. Four-Coordinate Phosphinidene Complexes of Titanium Prepared by α-Hydrogen Migration: Phospha-Staudinger and Phosphaalkene Insertion Reactions, F. Basuli, J. Tomaszewski, J. C. Huffman, D. J. Mindiola, J. Am. Chem. Soc. 2003, 125, 10170-10171. PDF
26. Snapshots of an Oxidatively Induced α-Hydrogen Abstraction Reaction to Prepare a Four-Coordinate Titanium Imide, F. Basuli, B. C. Bailey, J. C. Huffman, D. J. Mindiola, Chem. Commun. 2003, 1554-1555. PDF
25. A Terminal and Four-Coordinate Titanium Alkylidene Prepared by Oxidatively Induced α-Hydrogen Abstraction, F. Basuli, B. C. Bailey, J. Tomaszewski, J. C. Huffman, D. J. Mindiola, J. Am. Chem. Soc. 2003, 125, 6052-6053. PDF
Post-doctoral
24. Carbon–Hydrogen Bond Activation, C–N Bond Coupling, and Cycloaddition Reactivity of a Three-Coordinate Nickel Complex Featuring a Terminal Imido Ligand. Daniel J. Mindiola, Rory Waterman, Vlad M. Iluc, Thomas R. Cundari, and Gregory L. Hillhouse,Inorg. Chem. ASAP article online. PDF
23. Synthesis, Structure and Reactivity of Platinum Compounds Featuring Terminal Amido and Phosphido Ligands. Rory Waterman, Daniel J. Mindiola, Christopher Clough, and Gregory L. Hillhouse, Inorg. Chimica Acta (special issue in honor of Prof. T. Don Tilley) 2014, 422, 57-64. PDF
22. Functionalization of Complexed N2O in Bis(pentamethylcyclopentadienyl) Systems of Zirconium and Titanium. Daniel J. Mindiola, Lori A. Watson, Karsten Meyer, and Gregory L. Hillhouse, Organometallics 2014, 33, 2760-2769. PDF
21. Preparation of Stable Alkyl Complexes of Ni(I) and Their 1-Electron Oxidation to Ni(II) Complex Cations. Kristina D. Kitiachvili, Daniel J. Mindiola, Gregory L. Hillhouse, J. Am. Chem. Soc. 2004, 126, 10554-10555. PDF
20. Synthesis of 1,2-Bis(di-tert-butylphosphino)ethane (dtbpe) Complexes of Nickel: Radical Coupling and Reduction Reactions Promoted by the Nickel(I) Dimer [(dtbpe)NiCl]2, Daniel J. Mindiola, Rory Melenkivitz, David M. Jenkins, Gregory L. Hillhouse, Special issue dedicated to Prof. R. R. Schrock, Inorg. Chim. Acta. 2003, 345, 299-308. PDF
19. Synthesis, Structure, and Reactions of a Three-Coordinate Nickel-Carbene Complex, {1,2-Bis(di-tert-butylphosphino)ethane}Ni=CPh2, Daniel J. Mindiola and Gregory L. Hillhouse, J. Am. Chem. Soc. 2002, 124, 9976-9977. PDF
18. Isocyanate and Carbodiimide Synthesis by Nitrene-Group-Transfer from a Nickel Imido Complex, Daniel J. Mindiola and Gregory L. Hillhouse, Chem. Commun. 2002, 1840-1841. PDF
17. Monomeric Phosphido and Phosphinidene Complexes of Nickel, R. Melenkivitz, Daniel J. Mindiola and Gregory L. Hillhouse, J. Am. Chem. Soc. 2002, 124, 3846-3847. PDF
16. Terminal Amido and Imido Complexes of Three-Coordinate Nickel, Daniel J. Mindiola and Gregory L. Hillhouse, J. Am. Chem. Soc. 2001, 123, 4623-4624. PDF
Graduate
15. Niobaziridine Hydrides. Joshua S. Figueroa, Nicholas A. Piro, Daniel J. Mindiola, Michael G. Fickes, Christopher C. Cummins (Prof. Dietmar Seyferth Festschrift) Organometallics 2010, 29, 5215-5229. PDF
14. Radical Scission of Symmetrical 1,4-Dicarbonyl Compounds: C-C Bond Cleavage with Ti(IV) Enolate Formation and Related Reactions, Theodore Agapie, Paula L. Diaconescu, Daniel J. Mindiola, Christopher C. Cummins, Organometallics 2002, 21, 1329-1340. PDF
13. Probing the Niobium Metallaaziridine Functionality, Daniel J. Mindiola, Christopher C. Cummins, Organometallics 2001, 20, 3626-3628. PDF
12. Bimetallic μ-Cyanoimide Complexes Prepared by NCN Group Transfer, Daniel J. Mindiola, Yi-C. Tsai, Q. Chen, R. Hara, Thomas A. Baker, Karsten Meyer, Christopher C. Cummins, Chem. Commun. 2001, 125-126. PDF
11. Uranium Hexakisamido Complexes, Karsten Meyer, Daniel J. Mindiola, Tom A. Baker, William M. Davis, Christopher C. Cummins, Angew. Chem. Int. Ed., Engl. 2000, 39, 3063-3066. PDF
10. Arene-Bridged Diuranium Complexes: Inverted Sandwiches Supported by Delta Backbonding, Paula L. Diaconescu, Polly L. Arnold, Thomas A. Baker, Daniel J. Mindiola, Christopher C. Cummins, J. Am. Chem. Soc. 2000, 122, 6108-6109. PDF
9. Dinitrogen Cleavage Stemming from a Heterodinuclear Niobium/Molybdenum N2 Complex: New Nitridoniobium Systems Including a Niobazene Cyclic Trimer, Daniel J. Mindiola, Karsten Meyer, John P.-F. Cherry, Thomas A. Baker, Christopher C. Cummins, Organometallics, 2000, 19, 1622-1624. PDF
8. A Cyclometallated Resting State for a Reactive Molybdenum Amide: Favorable Consequences of beta-Hydrogen Elimination Including Reductive Cleavage, Coupling and Complexation, Yi-C. Tsai, Marc J. A. Johnson, Daniel J. Mindiola, W. T. Klooster, Thomas F. Koetzle, Christopher C. Cummins, J. Am. Chem. Soc. 1999, 121, 10426-10427. PDF
7. Redox-Catalyzed Binding of Dinitrogen by Molybdenum N-tert-Hydrocarbylanilide Complexes: Implications for Dinitrogen Functionalization and Reductive Cleavage, Jonas C. Peters, John P. -F. Cherry, Chris Thomas, Luis Baraldo, Daniel J. Mindiola, Christopher C. Cummins, J. Am. Chem. Soc. 1999, 121, 10053-10067. PDF
6. A Nucleophilic Chromium(V) Dioxo Radical Anion, Aaron L. Odom, Daniel J. Mindiola, Christopher C. Cummins, Inorg. Chem. 1999, 38, 3290-3295. PDF
5. Deprotonated 2,3:5,6-Dibenzo-7-azabicyclo[2.2.1]hepta-2,5-diene as a Nitrido Nitrogen Source via Anthracene Elimination, Daniel J. Mindiola, Christopher.C. Cummins, Angew. Chem. Int. Ed., Engl. 1998, 37, 945-948. PDF
Undergraduate
4. Reactions of DNA Purines with Rhodium Formamidinate Compounds that Display Antitumor Behavior, K. V. Catalan, J. S. Hess, M. M. Maloney, D. J. Mindiola, D. L. Ward, K. R. Dunbar, Inorg. Chem. 1999, 38, 3904-3913. PDF
3. A Quadruply-Bonded Dirhenium Complex Bridged by Two N1/N6 Adenate Ligands, M. E. Prater, D. J. Mindiola, X. Ouyang, K. R. Dunbar, Inorg. Chem. Commun. 1998, 1, 475-477. PDF
2. A Novel Dirhodium Compound with Neutral, Bridging 9-Ethyladenine, K. V. Catalan, D. J. Mindiola, D. L. Ward, and K. R. Dunbar, Inorg. Chem. 1997, 36, 2458-2460. PDF
1. Acetyltransfer Precedes Uridylyltransfer in the Formation of UDP-N-acetylglucosamine in Separable Active Sites of the Bifunctional GlmU Protein of Escherichia coli, E. D. Brown, A. M. Gehring, J. L. Watson J., D. J. Mindiola, C. T. Walsh, Biochemistry 1996, 35, 579-585. PDF