Scientific Contributions
Publications (*denotes contribution from undergraduate co-authors, which have been underlined)
Professor
2022
215. Isostructural Bridging Diiron Chalcogenide Cores [FeII(m-E)FeII] (E = O, S, Se, Te) with Decreasing Antiferromagnetic Coupling Down the Chalcogenide Series. Ethan Zars, Lisa Gravogl, Michael R. Gau, Patrick J. Carroll, Karsten Meyer, and Daniel J. Mindiola, Manuscript in preparation.
214. Reductive Coupling of a Titanium Nitride with Isocyanide to Form a Terminal Carbodiimide That is Probed in Three Oxidation States. Mrinal Bhunia, Lauren N. Grant, Dominik Fehn, Michael R. Gau, Karsten Meyer, Balazs Pinter, and Daniel J. Mindiola, Manuscript in preparation.
213. Pnictogen-Based Vanadacyclobutadiene Complexes. Mehrafshan G. Jafari, Bimal Pudasaini, Patrick J. Carroll, Mu-Hyun Baik, and Daniel J. Mindiola, Manuscript in preparation.
212. Ligand Non-Innocence Allows Isolation of a Neutral and Terminal Niobium Nitride. Shuruthi Senthil, Seongyeon Kwon, Hoyoung Im, Michael R. Gau, Patrick J. Carroll, Mu-Hyun Baik, and Daniel J. Mindiola. Chem. Commun. 2022, 58, 11795-11798 (HOT Articles for 2022). PDF
211. Metal-Ligand Cooperativity to Assemble a Neutral and Terminal Nb≡P Bond. Shuruthi Senthil, Seongyeon Kwon, Dominik Fehn, Hoyoung Im, Michael R. Gau, Patrick J. Carroll, Mu-Hyun Baik, Karsten Meyer, and Daniel J. Mindiola. Angew. Chem. Int. Ed. (Accepted Articles and Hot paper) PDF
210. High-Throughput Experimentation for Resource-Efficient Discovery of Methane Functionalization Catalysts.Orion Staples, Jacob S. Mohar, and Daniel J. Mindiola. In The power of high-throughput experimentation: Accelerating synthetic development and reaction discovery. ACS Books, Eds. Marion H. Emmert, Matthieu Jouffroy, and Dave Leitch. 2022, Chapter 8, Vol. 2, pp 123-145. PDF
209. Terminal and Super Basic Parent Imides of Hafnium. Mrinal Bhunia, Christian Sandoval-Pauker, Mehrafshan G. Jafari, Lauren N. Grant, Michael R. Gau, Balazs Pinter, and Daniel J. Mindiola, Angew. Chem. Int. Ed. (Hot paper), Early View. PDF
208. Alkylidene Complexes of Group 4 Transition Metals. Rolando Aguilar-Calderón, Pavel Zatsepin, and Daniel J. Mindiola, Book Chapter. Alkylidene complexes of the group 4 metals for Comprehensive Organometallic Chemistry IV. 2022, 3, 347-381. PDF
207. Ditelluride, Terminal Tellurido and Bis(Tellurido) Motifs of Titanium. Pavel Zatsepin, Jun-Hyeong Kim, Michael R. Gau, Patrick J. Carroll, Gang Wu, Mu-Hyun Baik, and Daniel J. Mindiola, J. Am. Chem. Soc.2022, 144, 13066-13070. PDF
206. Integrated Experimental and Computational K-edge XANES Analysis of Vanadium Catalysts Prajay Patel , Zheng Lu , Mehrafshan G. Jafari, Cristina Hernández-Prieto, Pavel Zatsepin, Daniel J. Mindiola, David M. Kaphan, Massimiliano Delferro, A. Jeremy Kropf, Cong Liu, J. Phys. Chem. C 2022, 126, 11949-11962. PDF
205. A Tale of Three Molecular Nitrides: Mononuclear Vanadium(V) and Vanadyl Nitrides, As Well As a Mixed-Valence Trivanadium Nitride Having a V3N4 core. Mehrafshan G. Jafari, Dominik Fehn,Cristina H. Prieto, Prajay Patel, Cong Liu, Anders Reinholdt, Michael R. Gau, Patrick J. Carroll, Jurek Krzystek, Andrew Ozarowski, Kyle Lancaster, Joshua Telser, Massimiliano Delferro, Karsten Meyer, and Daniel J. Mindiola, J. Am. Chem. Soc. 2022, 144, 10201-10219. PDF
204. Iron(II) Mediated Deazotation of Benzyl Azide: Trapping and Subsequent Transformations of the Benzaldimine Fragment. Ethan Zars, Lisa Gravogl, Michael Gau, Patrick J. Carroll, Karsten Meyer, and Daniel J. Mindiola, Inorg. Chem. 2022, 61, 1079-1090. PDF
203. An Isolable Azide Adduct of Titanium(II) Follows Bifurcated Deazotation Pathways to an Imide. Anders Reinholdt, Seongyeon Kwon, Mehrafshan G. Jafari, Michael R. Gau, Patrick J. Caroll, Chad Lawrence, Jun Gu, Mu-Hyun Baik, Daniel J. Mindiola, J. Am. Chem. Soc. 2022, 144, 527-537. PDF
2021
202. Chromium(III) Complexes. Orion Staples, Anders Reinholdt, and Daniel J. Mindiola, In Comprehensive Coordination Chemistry III; Constable, E. C., Parkin, G., Que Jr, L., Eds., Vol. 4, Elsevier, 2021; pp 508-551. website
201. Chromium(II) Complexes. Orion Staples, Anders Reinholdt, and Daniel J. Mindiola, In Comprehensive Coordination Chemistry III; Constable, E. C., Parkin, G., Que Jr, L., Eds., Vol. 4, Elsevier, 2021; pp 478-507. website
200. Niobium. Takashi Kurogi and Daniel J. Mindiola, In Comprehensive Coordination Chemistry III; Constable, E. C., Parkin, G., Que Jr, L., Eds., Vol. 4, Elsevier, 2021; pp 299-374. website
199. Titanium. Lauren N. Grant, J. Rolando Aguilar-Calderón, and Daniel J. Mindiola, In Comprehensive Coordination Chemistry III; Constable, E. C., Parkin, G., Que Jr, L., Eds., Vol. 4, Elsevier, 2021; pp 97-61. website
198. Mindiola, D. J. Transition Metal Groups 3–6: An Introduction. In Comprehensive Coordination Chemistry III; Constable, E. C., Parkin, G., Que Jr, L., Eds., Vol. 4, Elsevier, 2021; pp 1-4. website
197. P-Atom Transfer from Phosphaethynolate to an Alkylidyne. Mehrafshan G. Jafari, Yerin Park, Bimal Pudasaini, Takashi Kurogi, Patrick J. Carrol, David M. Kaphan, Jeremy Kropf, Massimiliano Delferro, Mu-Hyun Baik, and Daniel J. Mindiola, Angew. Chem. Int. Ed. 2021, 60, 24411-24417. PDF
196. Redox-Controlled and Reversible N−N Bond Forming and Splitting with a IronIV Terminal Imido Ligand. J. Rolando Aguilar-Calderón, Dominik Fehn, Dieter Sorsche, Matthias Miehlich, Patrick J. Carroll, Michael Gau, Karsten Meyer, and Daniel J. Mindiola, Inorg. Chem. 2021, 60, 17, 13091–13100. PDF
195. P and As Atom Transfer to Isocyanide to Form π-Backbonding Cyanophosphide and Cyanoarsenide Titanium Complexes. Anders Reinholdt, Mehrafshan G. Jafari, Christian Sandoval-Pauker, Ernesto Ballestero-Martínez, Michael R. Gau, Matthias Driess, Balazs Pinter, and Daniel J. Mindiola, Angew. Chem. Int. Ed. 2021, 60, 17595-17600. PDF
194. Pursuit of an Electron Deficient Titanium Nitride. Lauren N. Grant, Mrinal Bhunia, Balazs Pinter, Christophe Rebreyend, Maria E. Carroll, Patrick J. Carroll, Bas de Bruin, and Daniel J. Mindiola. Inorg. Chem. 2021, 60, 5635-5646. PDF
2020
193. A Mononuclear and High-Spin Tetrahedral TiII Complex. Anders Reinholdt, Daniel Pividori, Alexander Laughlin, Idda M. DiMucci, Samantha N. MacMillan, Mehrafshan G. Jafari, Michael Gau, Patrick J. Carroll, J. Krzystek, Andrew Ozarowski, Joshua Telser, Kyle M. Lancaster, Karsten Meyer, and Daniel J. Mindiola , Inorg. Chem. (ACS Editors' choice) 2020, 59, 17834-17850. PDF Most viewed paper in this journal for several consecutive months with over 14K views!
192. Methylidyne Transfer and Exchange as a Plausible Deactivation Pathway for Cyclic-Polynorbornene Catalysts. Takashi Kurogi, Zhihui Miao, and Daniel J. Mindiola, Organometallics 2020, 39, 4474-4478. PDF
191. Editorial for the special issue "Organometallic Chemistry at Various Length Scales": More Than Just Metal-Carbon Bonds Bring Chemists Together. Daniel J. Mindiola, Massimiliano Delferro, and Simon M. Humphrey, Organometallics 2020, 39, 881-882. PDF
190. Electronic Structure and Magnetic Properties of a Titanium(II) Coordination Complex. Eva M. Zolnhofer, Gayan B. Wijeratne, Timothy A. Jackson, Skye Fortier, Frank W. Heinemann, Karsten Meyer, J. Krzystek, Andrew Ozarowski, Daniel J. Mindiola, and Joshua Telser, Inorg. Chem. (ACS Editors' choice) 2020, 59, 6187-6201. PDF
189. Tebbe-Like and Phosphonioalkylidene and -alkylidyne Complexes of Scandium. Pavel Zatsepin, Eunji Lee, Jun Gu, Michael R. Gau, Mu-Hyun Baik, and Daniel J. Mindiola, J. Am. Chem. Soc. 2020, 142, 10143-10152. PDF
188. Pioneers and Influencers: Dr. Patricia Watson and the Molecular Dance of M-C and C-H Bonds. Daniel J. Mindiola,Organometallics 2020, 39, 1135-1138. PDF
187. Reversible chelation and η5-pyrrolyl coordination in a [Cp*Ir]2+ fragment. Orion Staples, Michael R. Gau and Daniel J. Mindiola, Organometallics 2020, 39, 1145-1148. PDF
186. Selenenate Anions (PhSeO–) as Organocatalyst: Synthesis of trans-Stilbenes and a PPV Derivative. Zhipeng Zheng, Oleksandra S. Trofymchuk, Takashi Kurogi, Elena Varela, Daniel J. Mindiola, and Patrick J. Walsh, Adv. Synth. Catal. 2020, 362, 659-666. PDF
185. Unusual Dinitrogen Binding and Electron Storage in Dinuclear Iron Complexes. Dieter Sorsche, Matthias E. Miehlich, Keith Searles, Guillaume Gouget, Eva M. Zolnhofer, Skye Fortier, Chun-Hsing Chen, Michael Gau, Patrick J. Carroll, Christopher B. Murray, Kenneth G. Caulton, Marat M. Khusniyarov, Karsten Meyer, Daniel J. Mindiola, J. Am. Chem. Soc. 2020, 142, 8147-8159. PDF
184. Werner-Like Complexes of Uranium(III) and (IV). Judith Riedhammer, J. Rolando Aguilar-Calderón, Matthias Miehlich, Dominik P. Halter, Dominik Munz, Frank W. Heinemann, Skye Fortier, Karsten Meyer and Daniel J. Mindiola, Inorg. Chem. 2020, 59, 2443-2449. PDF
2019
183. The Rise of Phosphaethynolate Chemistry in Early-Transition Metals, Actinides, and Rare-Earth Complexes. Lauren N. Grant and Daniel J. Mindiola, Chem. Eur. J. (Invited Concepts Paper) 2019, 25, 16171-16178. PDF
182. Scrutinizing Metal-Ligand Covalency and Redox Non-Innocence Via Nitrogen K-edge X-ray Absorption Spectroscopy. James T. Lukens, Ida M. DiMucci, Tadashi Kurogi, Daniel J. Mindiola, and Kyle M. Lancaster, Chem. Sci. 2019, 10, 5044-5055. PDF
181. Neutral and Anionic Monomeric Zirconium Imides Prepared via Selective C=N Bond Cleavage of a Multidentate and Sterically Demanding β-Diketiminato Ligand. Takashi Kurogi, Jiaxiang Chu, Yaofeng Chen, and Daniel J. Mindiola, Chem. Asian J. 2019, 14, 2629-2638. PDF
180. Finding a Soft Spot for Vanadium: A P-Bound OCP Ligand. Lauren N. Grant, J. Krzystek, Andrew Ozarowski, Joshua Telser, Hansjӧrg Grützmacher, and Daniel J. Mindiola, Chem. Commun. 2019, 55, 5966-5969. PDF
179. "Catalytic Borylation of Methane: Combining Computational and High-Throughput Screening Approaches to Discover A New Catalyst" In Alkane Functionalization (Ed. Pombeiro, A. J. L.; Guedes da Silva, M. F. C.), J. Wiley publisher. Pavel Zatsepin, Dieter Sorsche, Seihwan Ahn, Mu-Hyun Baik, and Daniel J. Mindiola, in Press.
178. Well-Defined Titanium Complex for Free-Radical and Cationic Photopolymerizations under Visible Light and Photoinduction of Ti-Based Nanoparticles. Louise Breloy, Vlasta Brezova, Jean-Pierre Malval, Agustin Rios de Anda, Julie Bourgon, Takashi Kurogi, Daniel J. Mindiola, and Davy-Louis Versace, Macromolecules 2019, 52, 3716-3729. PDF
177. Conversion of Methane to Ethylene Using an Iridium Complex and Phosphorus Ylide as a Methylene Transfer Reagent. Pavel Zatsepin, Seihwan Ahn, Bimal Pudasaini, Michael R. Gau, Mu-Hyun Baik, and Daniel J. Mindiola, Chem. Commun. 2019, 55, 1927-1930. PDF
2018
176. A Molecular Zirconium Nitride Super Base from a Mononuclear Parent Imide. Lauren N. Grant, Balazs Pinter, Jun Gu, and Daniel J. Mindiola, J. Am. Chem. Soc. 2018, 140, 17399-17403. PDF
175. Rational Design of a Catalyst for the Selective Monoborylation of Methane. Seihwan Ahn, Dieter Sorsche, Ho Ryu, Simon Berritt, Michael R. Gau, Daniel J. Mindiola, and Mu-Hyun Baik, ACS Catal. 2018, 8, 10021-10031. PDF
174. Editorial for Frontiers in Coordination Chemistry and its Applications. Michael Shatruk, Eric Schelter, and Daniel J. Mindiola. Special Issue to Honor Professor Kim R. Dunbar on the occasion of her 60th birthday. Dalton Trans. 2018, 47, 11736-11738. PDF
173. Metal-Ligand Cooperativity Promoting Sulfur-Atom Transfer in Ferrous Complexes and Isolation of a Sulfurmethylenephosphorane Adduct. Dieter Sorsche, Matthias Miehlich, Eva M. Zolnhofer, Patrick J. Carroll, Brian C. Manor, Karsten Meyer, and Daniel J. Mindiola, Inorg. Chem. 2018, 57, 11552-11559. PDF
172. C–H Bond Addition Across a Transient Uranium Nitrido and Formation of a Parent Uranium Imido Complex. Kimberly C. Mullane, Ho Ryu, Thibault Cheisson, Lauren N. Grant, Ji Young Park, Brian C. Manor, Patrick J. Carroll, Mu-Hyun Baik, Daniel J. Mindiola, and Eric J. Schelter, J. Am. Chem. Soc. 2018, 140, 11335-11340. PDF
171. Methylidyne Transfer Reactions with Niobium. Takashi Kurogi, Balazs Pinter, and Daniel J. Mindiola, Organometallics (special issue in honor of Prof. Ernesto Carmona) 2018, 37, 3385-3388. PDF
170. Selenolate Anion as an Organocatalyst: Reactions and Mechanistic Studies. Oleksandra S. Trofymchuk, Zhipeng Zheng, Takashi Kurogi, Daniel J. Mindiola, and Patrick J. Walsh, Adv. Synth. Catal. 2018, 360, 1685-1692. PDF
169. Divergent Pathways Involving 1,3-Dipolar Addition and N-N Bond Splitting of an Organic Azide Across a Zirconium Methylidene, Takashi Kurogi, Mane Manoj, Shuai Zheng, Patrick J. Carroll, Mu-Hyun Baik,* and Daniel J. Mindiola, Angew. Chem. Int. Ed. 2018, 57, 1978-1981. PDF
168. Room Temperature Olefination of Methane with Titanium-Carbon Multiple Bonds. Takashi Kurogi, Joonghee Won, Bohyun Park, Oleksandra S. Trofymchuk, Patrick J. Carroll, Mu-Hyun Baik, and Daniel J. Mindiola, Chem. Sci. 2018, 9, 3376-3385. PDF Manuscript highlighted by Chemistry World (RSC). website
167. A Scandium Stabilized Diisophosphaethynolate Ligand, [OCPPCO]4−. Lauren N. Grant, Balazs Pinter, Brian C. Manor, Hansjӧrg Grützmacher, and Daniel J. Mindiola, Angew. Chem. Int. Ed. 2018, 57, 1049-1052. PDF
166. Arrested Disproportionation in Trivalent, Mononuclear, and Non-Metallocene Complexes of Zr(III) and Hf(III). Lauren N. Grant, Matthias E. Miehlich, Karsten Meyer, and Daniel J. Mindiola, Chem. Commun. 2018, 54, 2052-2055. PDF
165. 1,2-CH Bond Activation of Pyridine Across a Transient Titanium Alkylidene Radical and Reformation of the Alkylidene Moiety. Takashi Kurogi, Matthias Miehlich, Dominik Halter, and Daniel J. Mindiola, Organometallics 2018, 37, 165-167. PDF
2017
164. Polyhydrides of Sc, Zr and Hf and Their Proposed Formation.Takashi Kurogi, Masahiro Kamitani, Patrick J. Carroll, and Daniel J. Mindiola, Israel J. Chem. (special issue dedicated to Prof. Robert Bergman for being awarded the Wolf Prize in Chemistry) 2017, 57, 999-1009. PDF
163. Room Temperature Ring-Opening of Quinoline, Isoquinoline and Pyridine with Low-Valent Titanium. Seung-yeol Baek, Takashi Kurogi, Dahye Kang, Masahiro Kamitani, Seongyeon Kwon, Douglas P. Solowey, Chun-Hsing Chen, Maren Pink, Patrick J. Carroll, Daniel J. Mindiola, and Mu-Hyun Baik, J. Am. Chem. Soc. 2017, 139, 12804-12814. PDF
162. Trimethylsilyl Imide Complexes of Tantalum: Can The Silyl Group Be Eliminated? Takashi Kurogi, Patrick J. Carroll, Brian C. Manor, and Daniel J. Mindiola, Polyhedron ( Special issue in applications of tridentate and tetradentate tripodal ligands) 2017, 125, 80-85. PDF
161. A New and Selective Cycle for Dehydrogenation of Linear and Cyclic Alkanes Under Mild Conditions Using a Base Metal. Douglas P. Solowey, Manoj V. Mane, Takashi Kurogi, Patrick J. Carroll, Brian C. Manor, Mu-Hyun Baik, and Daniel J. Mindiola, Nat. Chem. 2017, 9, 1126-1132. PDF Manuscript highlighted by Nat. Chem. PDF and the University of Pennsylvania. website
160. A Radical Coupled Pathway to a Stable and Terminally Bound Titanium Methylidene. Takashi Kurogi, Patrick J. Carroll, and Daniel J. Mindiola, Chem. Commun. 2017, 53, 3412-3414. Back-to-back articles chosen for front art cover. PDF
159. Structural elucidation of a mononuclear titanium methylidene. Lauren N. Grant, Seihwan Ahn, Brian C.Manor, Mu-Hyun Baik, and Daniel J. Mindiola, Chem. Commun. 2017, 53, 3415-3417. Back-to-back articles chosen for front art cover. PDF
158. A Planar Ti2P2 Core Assembled by Reductive Decarbonylation of -O-C≡P and P-P Radical Coupling. Lauren N. Grant, Balazs Pinter, Brian C. Manor, Riccardo Suter, Hansjӧrg Grützmacher, and Daniel J. Mindiola, Chem. Eur. J. 2017, 23, 6272-6276 (selected as a hot paper). PDF
157. Reactivity Studies of a Zirconium Methylidene Complex: Group Transfer and Methylenation Reactions. Takashi Kurogi, Masahiro Kamitani, Brian C. Manor, Patrick J. Carroll, and Daniel J. Mindiola, Organometallics (special issue Hydrocarbon Chemistry: Activation and Beyond) 2017, 36, 74-79. PDF
156. Editorial for the special issue Hydrocarbon Chemistry: Activation and Beyond. Responsible or Irresponsible Use of Hydrocarbons? You be the Judge! Daniel J. Mindiola, Organometallics 2017, 36, 5-7 (art cover for special issue). PDF
155. Molecular Titanium Nitrides: Nucleophiles Unleashed. Lauren N. Grant, Balazs Pinter, Takashi Kurogi, Maria E Carroll, Gang Wu, Brian Manor, Patrick Carroll and Daniel J Mindiola, Chem. Sci. 2017, 8, 1209-1224. PDF
2016
154. The Value of Stable Metal-Carbon Bonds in Nuclear Medicine and the Cardiolite Story. James F. Kronauge and Daniel J. Mindiola, Organometallics 2016, 35, 3432-3435. PDF
153. Metallo-Wittig Chemistry of an Alkylidene to Form a Terminal Titanium Oxo Complex. Doug Solowey, Takashi Kurogi, Brian Manor, Patrick J. Carroll, and Daniel J. Mindiola. Dalton Trans. (Special Issue on Reactions Facilitated by Ligan Design). 2016, 45, 15894-15901. PDF
152. An Editorial on Elemental Analysis. Francois P. Gabbai, Paul J. J. Chirik, Deryn E. Fogg, Karsten Meyer, Daniel J. Mindiola, Laurel L. Schafer and Shu-Li You, Organometallics 2016, 35, 3255-3256. PDF
151. An Unusual Cobalt Azide Adduct that Produces A Nitrene Species for C-H Insertion Chemistry. Lauren N. Grant, Maria E. Carroll, Patrick J. Carroll, and Daniel J. Mindiola, Inorg. Chem. 2016, 55, 7997-8002. PDF
150. A Terminally Bound Niobium Methylidyne. Takashi Kurogi, Patrick J. Carroll, and Daniel J. Mindiola. J. Am. Chem. Soc. 2016, 138, 4306-4309. PDF
149. Formation and Redox Interconversion of Niobium Methylidene and Methylidyne Complexes. Keith Searles, Kyle T. Smith, Takashi Kurogi, Chun-Hsing Chen, Patrick J. Carroll, and Daniel J. Mindiola, Angew. Chem. Int. Ed. 2016, 55, 6642-6645. PDF
148. Catalytic Borylation of Methane. Kyle T. Smith, Simon Berritt, Mariano Gónzales-Moreiras, Seihwan Ahn, Milton R. Smith III, Mu-Hyun Baik, and Daniel J. Mindiola, Science 2016, 351, 1424-1427. PDFHighlight by Science Magazine. PDF
2015
147. Gregory L. Hillhouse. His Life, His Art, His Science, and the Rise of “Double Nickel”. Daniel J. Mindiola, Milton Smith III, and John E. Bercaw, Organometallics 2015, 34, 4633-4636 (art cover for special issue dedicated to Prof. Hillhouse). PDF
146. Anionic and Mononuclear Phosphinidene and Imide Complexes of Niobium. Keith Searles, Patrick J. Carroll, and Daniel J. Mindiola, Organometallics 2015, 34, 4641-4643. PDF
145. Phosphinoalkylidene and -alkylidyne Complexes of Titanium: Intermolecular C–H Bond Activation and Dehydrogenation Reactions. Masahiro Kamitani, Keith Searles, Marco G. Crestani, Anne Hickey, Brian C. Manor, Patrick J. Carroll, and Daniel J. Mindiola, J. Am. Chem. Soc. 2015, 137, 11872-11875. PDF
144. Cyclo-P3 Complexes of Vanadium: Redox Properties and the Origin of the 31P NMR Chemical Shift." Balazs Pinter, Kyle T. Smith, Masahiro Kamitani, Eva M. Zolnhofer, Ba L. Tran, Skye Fortier, Maren Pink, Gang Wu, Brian C. Manor, Karsten Meyer, Mu-Hyun Baik, and Daniel J. Mindiola, J. Am. Chem. Soc. 2015, 137, 15247–15261. PDF
143. Mononuclear and Terminally Bound Titanium Nitrides. Maria E. Carroll, Balazs Pinter, Patrick J. Carroll, and D. J. Mindiola, J. Am. Chem. Soc. 2015, 137, 8884-8887. PDF
142. Niobium-Nitrides Derived from Nitrogen Splitting. Keith Searles, Patrick J. Carroll, Chun-Hsing Chen, Maren Pink and D. J. Mindiola. Chem. Commun 2015, 51, 3526-3528. PDF
141. Synthesis of an Iron(II) Ethyl Complex Accompanied by Formation of an Unusual Dinitrogen-Ligated Iron(I) Hydride. Lindsay J. Hounjet, Debashis Adhikari, Maren Pink, Patrick J. Carroll, and Daniel J. Mindiola. Zeitschrift für Anorganische und Allgemeine Chemie (Special issue on Reactive Nitrogen-Containing Species: Generation, Characterization and Functionalization) 2015, 641, 45-48. PDF
140. Electronic Structure and Reactivity of a Well-Defined Mono-nuclear Complex of Ti(II). Skye Fortier, Timothy A. Jackson, Gayan B. Wijeratne, Chun-Hsing Chen, Patrick J. Caroll, Eva M. Zolnhofer, Lauren N. Grant, Karsten Meyer, J. Krzystek, Andrew Ozarowski, Daniel J. Mindiola, and Joshua Telser, Inorg. Chem. 2015, 54, 10380-10397. PDF
139. Addition of Si-H and B-H Bonds and Redox Reactivity Involving Low-Coordinate Nitrido Vanadium Complexes. Rick Thompson, Ba L. Tran, Soumya Ghosh, Chun-Hsing Chen, Maren Pink, Xinfeng Gao, Patrick J. Carroll, Mu-Hyun Baik and Daniel J. Mindiola, Inorg. Chem. 2015, 54, 3068-3077. PDF
138. β-Hydrogen Abstraction of an Ethyl Group Provides Entry to Stable Titanium and Zirconium Ethylene Complexes. Masahiro Kamitani, Keith Searles, Chun-Hsing Chen, Patrick J. Carroll, and Daniel J. Mindiola, Organometallics 2015, 34, 2558-2566 (Special Issue honoring the late Prof. Michael Lappert). PDF
2014
137. A cis-Divacant Mononuclear Iron(IV) Imide. Keith Searles, Skye Fortier, Marat Khusniyarov, Chin-Hsing Chen, Maren Pink, Patrick J. Carroll, Jörg Sutter, Karsten Meyer, Daniel J. Mindiola, and Kenneth G. Caulton, Angew. Chem. Int. Ed. 2014, 53, 14139-14143. PDF
136. Dehydrogenation of Hydrocarbons with Metal-Carbon Multiple Bonds and Trapping of a Titanium(II) Intermediate. Anne Hickey, Marco G. Crestani, Alison R. Fout, Xinfeng Gao, Chun-Hsing Chen, and Daniel J. Mindiola, Dalton Trans. 2014, 43, 9834-9837. PDF
135. A Nitrido Salt Reagent of Titanium. Rick Thompson, Gang Wu, Chun-Hsing Chen, Maren Pink, and Daniel J. Mindiola, J. Am. Chem. Soc. 2014, 136, 8197-8200. PDF
134. Mononuclear Zirconium and Hafnium Methylidenes. Masahiro Kamitani, Balazs Pinter, Chun-Hsing Chen, Maren Pink, and Daniel J. Mindiola, Angew. Chem. Int. Ed. 2014, 53, 10913-10915 (hot paper and selected for front cover of journal). PDF
133. N-N Bond Cleavage in Diazoalkanes with a Titanium Alkylidenes. Jun-ichi Ito, Marco G. Crestani, Brad C. Bailey, Xinfeng Gao, and Daniel J. Mindiola, Polyhedron 2014, 84, 177-181 (Special Issue dedicated to Prof. John Bercaw). PDF
132. A Tantalum Methylidene Complex Supported by a Robust and Sterically Encumbering Aryloxide Ligand. Keith Searles, Balaz Pinter, Chun-Hsing Chen, Daniel J. Mindiola, Organometallics 2014, 33, 4192-4199. PDF
131. Transition Metal Chlorides are Lewis Acids towards Terminal Chloride Attached to Late Transition Metals, Alice K. Hui, Brian J. Cook, Daniel J. Mindiola, and Kenneth G. Caulton, Inorg. Chem. 2014, 53, 3307-3310. PDF
130. Hydrogen Abstraction of a Vinylic Hydrogen to Form Alkynes. Multidimensional and Multinuclear NMR Spectroscoscopic Studies Elucidating Structural Solution Behavior of Alkyne Complexes of Titanium. Anne Hickey, Marco G. Crestani, Balazs Pinter, Xinfeng Gao, and Daniel J. Mindiola, Organometallics 2014, 33, 1157-1173. PDF
129. Mechanistic Understanding of a Silver Pyridylpyrrolide as a Catalyst for 3+2 Cyclization of Nitrile with Diazoester. Jaime A. Flores, Kuntal Pal, Maria E. Carroll, Maren Pink, Jonathan A. Karty, Daniel J. Mindiola, and Kenneth G. Caulton. Organometallics 2013, 33, 1544-1552. PDF
128. Binary Role of an Ylide in Formation of a Terminal Methylidene Complex of Niobium. Keith Searles, Karlijn Keijzer, Chun-Hsing Chen, Mu-Hyun Baik, and Daniel J. Mindiola, Chem. Commun. 2014, 50, 6267-6269. PDF
127. Structural Elucidation of the Illustrous Tebbe Reagent. Rick Thompson, Eiko Nakamaru-Ogiso, Chun-Hsing Chen, Maren Pink, and Daniel J. Mindiola, Organometallics 2014, 33, 429-432. PDF C& E News, vol 92, page 21 (January 5, 2014). website
2013
126. Uranium(III) Complexes with Bulky Aryloxide Ligands Featuring Metal‒Arene Interactions and Their Reactivity Towards Nitrous Oxide. Sebastian M. Franke, Ba L. Tran, Frank W. Heinemann, Wolfgang Hieringer, Daniel J. Mindiola, and Karsten Meyer, Inorg. Chem. 2013, 52, 10552-10558. PDF
125. 3d Early Transition Metal Complexes Supported by a New Sterically Demanding Aryloxide Ligand. Keith Searles, Ba L. Tran, Maren Pink, Chun-Hsing Chen, and Daniel J. Mindiola, Inorg. Chem. 2013, 52, 11126-11135. PDF
Correction for the above manuscript: PDF
124. A Dinuclear Cobalt Complex Featuring Unprecedented Anodic and Cathodic Redox Switches for Single-Molecule Magnet Activity. Skye Fortier, Jennifer J. Le Roy, Chun-Hsing Chen, Veacheslav Vieru, Muralee Murugesu, Liviu F. Chibotaru, Daniel J. Mindiola, and Kenneth G. Caulton, J. Am. Chem. Soc. 2013, 135, 14670-14678. PDF
123. Room Temperature Dehydrogenation of Ethane, Propane, Linear Alkanes C4-C8, and Some Cyclic Alkanes by Titanium-Carbon Multiple Bonds. Marco G. Crestani, Anne K. Hickey, Xinfeng Gao, Balazs Pinter, Vincent N. Cavaliere, Jun-Ichi Ito,Chun-Hsing Chen, and Daniel J. Mindiola, J. Am. Chem. Soc. 2013, 135, 14754-14767. PDF
122. Formation and Reactivity of the Terminal Vanadium Nitride Functionality. Ba L. Tran, J. Krzystek, Andrew Ozarowski, Chung-Hsing Chen, Maren Pink, Jonathan A. Karty, Joshua Telser, Karsten Meyer and Daniel J. Mindiola, Eur. J. Inorg. Chem. (Special issue on small molecule activation) 2013, 3916-3929. PDF
121. Büchner Reactions Catalyzed by a Silver(I) Pyridylpyrrolide: Understanding Arene C=C Insertion Selectivity. Komine Nobuyuki, Jaime A. Flores, Kuntal Pal, Kenneth G. Caulton, and Daniel J. Mindiola, Organometallics 2013, 32, 3185-3191. PDF
120. Understanding Competitive Pathways Involving the Dehydroalkoxylation and Dehydrogenation of Ethers with Ti-C Multiple Bonds. Marco G. Crestani, Balazs Pinter, Andras Olasz, Brad C. Bailey, Skye Fortier, Xinfeng Gao, Chun-Hsing Chen, Mu-Hyun Baik, and Daniel J. Mindiola, Chem. Sci. 2013,4, 2543-2550. PDF
119. A Four-Coordinate Thionitrosyl Complex of Vanadium. Rick Thompson, Ba L. Tran, Soumya Ghosh, Xinfeng Gao, Chun-Hsing Chen, Mu-Hyun Baik, and Daniel J. Mindiola, Chem. Commun. 2013, 49, 2768-2770. PDF
118. 2,2’-Pyridylpyrrolide Ligand Redistribution Following Reduction. Keith Searles, Atanu K. Das, René W. Buell, Maren Pink, Chun-Hsing Chen, Kuntal Pal, David Gene Morgan, Daniel J. Mindiola, and Kenneth G. Caulton, Inorg. Chem. 2013, 52, 5611-5619. PDF
Correction for the above manuscript: PDF
117. Understanding Intermolecular C-F Bond Activation by a Transient Titanium Neopentylidyne. Experimental and Theoretical Studies Distinguishing Competitive Pathways such as 1,2-CF Bond Addition from [2+2]-Cycloaddition/β-Flouride Elimination. Hongjun Fan, Alison R. Fout, Brad C. Bailey, Maren Pink, Mu-Hyun Baik, and Daniel J. Mindiola, Dalton Trans. Special Issue in Organometallic Chemistry 2013, 42, 4163-4174. PDF
2012
116. Vanadocene de Novo: Spectroscopic and Computational Analysis of Bis(η5-cyclopentadienyl)vanadium(II). Joshua Telser, Timothy Jackson, Gayan Wijeratne, Daniel J.Mindiola, Benjamin F. Wicker, Jurek Krzystek, Andrew Ozarowski, Organometallics 2012, 31, 8265–8274. PDF
Correction for the above manuscript: PDF
115. Probing the redox non-innocence of dinuclear, three-coordinate Co(II) nindigo complexes: not simply β-diketiminate variants. Skye Fortier, Octavio González-del Moral, Chun-Hsing Chen, Maren Pink, Jennifer J. Le Roy, Muralee Murugesu, Daniel J. Mindiola, and Kenneth G. Caulton, Chem. Commun. 2012, 48, 11082-11084. PDF
114. An iridium-pyridylpyrrolide complex exhibiting reversible binding of H2. Keith Searles, Maren Pink, Kenneth G. Caulton, and Daniel J. Mindiola, Dalton Trans. 2012, 41, 9619-9622. PDF
113. New talent Issue: Americas. Daniel J. Mindiola, John Arnold, Theo Agapie, Jennifer Love and Mircea Dincă, Dalton Trans.(Editorial) 2012, 41, 7781. PDF
112.* A Planar Three-Coordinate Vanadium(II) Complex and Terminal Vanadium Nitrides from N2. A Kinetic or Thermodynamic Impediment? Ba L. Tran, Balazs Pinter, Adam J. Nichols, Chun-Hsing Chen, J. Krzystek, Andrew Ozarowski, Joshua Telser, Mu-Hyun Baik, Karsten Meyer, and Daniel J. Mindiola, J. Am. Chem. Soc. 2012, 134, 13035-13045. PDF
111. A Mononuclear Fe(III) Single Molecule Magnet with a 3/2 ↔ 5/2 Spin Crossover. Susanne Mossin, Ba L. Tran, Debashis Adhikari, Maren Pink, Frank W. Heinemann, Jörg Sutter, Robert K. Szilagyi, Karsten Meyer, and Daniel J. Mindiola, J. Am. Chem. Soc. 2012, 134, 13651-13661. PDF
110. Evidence for the Existence of Terminal Scandium Imidos. Mechanistic Studies Involving Sc=N Bond Formation and C-H Activation Reactions. Benjamin F. Wicker, Hongjun Fan, Anne K. Hickey, Marco G. Crestani, Jennifer Scott, Maren Pink, Mu-Hyun Baik, and Daniel J. Mindiola, J. Am. Chem. Soc. 2012, 134, 20081-20096. PDF
109. Homogeneous Organometallic Chemistry of Methane. Vincent N. Cavaliere, Benjamin F. Wicker, and Daniel J. Mindiola, Adv. Organomet. Chem. 2012, 60, 1-47. website
108. Methane: A New Frontier in Organometallic Chemistry. Vincent N. Cavaliere and Daniel J. Mindiola, Chem. Sci. 2012,3, 3356-3365. PDF
107.* A Four Coordinate Parent Imide Via a Titanium Nitridyl. Ba L. Tran, Marlena Washington, Danielle A. Henckel, Xinfeng Gao, Maren Pink, and Daniel J. Mindiola, Chem. Commun. 2012, 48, 1529-1531 (Invited contribution to the "New Talent" special issue). PDF
106. Silver(I)-Catalyzed Insertion of Carbene into Alkane C-H Bonds and the Origin of the Special Challenge of Methane Activation Using DFT as a Mechanistic Probe. Jaime A. Flores, Komine Nobuyuki, Kuntal Pal, Balazs Pinter, Maren Pink, Chun-Hsing Chen, Kenneth G. Caulton and Daniel J. Mindiola, ACS Catalysis 2012, 2, 2066-2078. PDF
2011
105. Isocyanide Insertion and Cyclization Reactions to Form Indolines Using Pincer-Type Complexes of Scandium. Benjamin F. Wicker, Maren Pink, and Daniel J. Mindiola, Dalton Trans. 2011, 40, 9020-9025 (Special themed issue: Pincers and other hemilabile ligands). PDF
104. 1,2-CF Bond Activation of Perfluoroarenes and Alkylidene Isomers of Titanium. DFT Analysis of the C-F Bond Activation Pathway and Rotation of the Titanium Alkylidene Moiety. José G. Andino, Hongjun Fan, Alison R. Fout, Brad C. Bailey, Mu-Hyun Baik, and Daniel J. Mindiola, J. Organomet. Chem. 2011, 696, 4138-4146 (special issue " Small Molecule Activation and Catalysis Invoking Metal-Carbon Multiple Bonds", which is dedicated to Professor Ken Caulton on the occasion of his 70th birthday). PDF
103. Biographical Sketch for Kenneth Caulton: J. Organomet. Chem. 2011, 696, 3910. PDF
102. Foreword to special issue on metal–carbon multiple bonds and the activation of small molecules. Richard D. Adams and Daniel J. Mindiola, J. Organomet. Chem. 2011, 696, 3909. PDF
101. Room Temperature Dehydrogenation of Ethane to Ethylene. Vincent N. Cavaliere, Marco G. Crestani, Balazs Pinter, Chun-Hsing Chen, Maren Pink, Mu-Hyun Baik, and Daniel J. Mindiola, J. Am. Chem. Soc. 2011, 133, 10700-10703. PDF C& E News, vol 89, page 26 (July 4, 2011). website
Author Profile: Daniel J. Mindiola, Angew. Chem. Int. Ed. 2011, 50, 4046. PDF
100. Reactivity Studies of a Pseudo Three-Coordinate Vanadium(II) Complex: Synthesis of Terminal Oxo and Sulfido Complexes of Vanadium(IV) and S-S and Se-Se Reductive Bond Cleavage Reactions. Ba L. Tran, Chun-Hsing Chen, and Daniel J. Mindiola, Inorg. Chim. Acta (Special Issue in Honor of Prof. Robert Bergman), 2011, 369, 215-222. PDF
99. Methane Activation and Exchange by Titanium-Carbon Multiple Bonds. Jaime A. Flores, Vincent N. Cavaliere, Dominik Buck, George Chen, Marco G. Crestani, Balazs Pinter, Mu-Hyun Baik, and Daniel J. Mindiola, Chem. Sci. 2011, 2, 1457-1462 (Front Cover of issue). PDF Highlighted by the RSC Chemistry World (June 2, 2011). website
98. Atom Economical Route to Substituted Pyridines via Scandium Imido. Benjamin F. Wicker, Jennifer Scott, Alison R. Fout, Maren Pink, and Daniel J. Mindiola, Organometallics 2011, 30, 2453-2456. PDF
97. Carbenes vs. Alkylidenes.Spot the Difference. Daniel J. Mindiola and Jennifer Scott, Nature Chem. 2011, 3, 15-17 (Invited News and Views). PDF
96. Understanding a Reactive and Easy-to-Prepare Titanium Carboamination Catalyst. Falguni Basuli, Benjamin Wicker, John C. Huffman, and Daniel J. Mindiola, J. Organomet. Chem. 2011, 696, 235-243. Invited Article for the thematic Issue Entitled "Catalytic Addition of E-H Bonds". PDF
Associate Professor
2010
95.* Reactivity Studies of a Masked Three-Coordinate Vanadium(II) Complex. Ba L. Tran, Madhavi Singhal, Hyunsoo Park, Oanh P. Lam, Maren Pink, J. Krzystek, Andrew Ozarowski, Joshua Telser, Karsten Meyer, and Daniel J. Mindiola, Angew. Chem. Int. Ed. 2010, 49, 9871-9875. PDF
94. Phosphinidene Complexes of Scandium. Powerful PAr Group-Transfer Vehicles to Organic and Inorganic Substrates. Benjamin F. Wicker, Jennifer Scott, José G. Andino, Xinfeng Gao, Maren Pink, and Daniel J. Mindiola J. Am. Chem. Soc. 2010, 132, 3691-3693. PDF
93. Low-Coordinate and Neutral Nitrido Complexes of Vanadium. Ba L. Tran, Maren Pink, Xinfeng Gao, Hyunsoo Park, and Daniel J. Mindiola, J. Am. Chem. Soc. 2010, 132, 1458-1459. PDF
92. Synthetic and Mechanistic Studies of Ring-Opening and Denitrogenation of Pyridine and Picolines. Alison R. Fout, Brad C. Bailey, Dominik Buck, Hongjun Fan, John C. Huffman, Mu-Hyun Baik, and Daniel J. Mindiola, (Prof. Dietmar Seyferth Festschrift) Organometallics 2010, 29, 5409-5422. PDF
91. Intermolecular C-H Bond Activation of Benzene and Pyridines by a Vanadium(III) Alkylidene Including a Stepwise Conversion of Benzene to a Vanadium-Benzyne Complex. José G. Andino, Uriah J. Kilgore, Andrew Ozarowski, J. Krzystek, Joshua Telser, Maren Pink, Mu-Hyun Baik, and Daniel J. Mindiola, Chem. Sci. 2010, 1, 351-356. PDF
90. Cobalt 2,2,6,6-tetramethyl-3,5-bis-(2,6-diisopropylphenylimido)heptyl chloride (L(tBu,iPr2)CoCl). Keying Y. Ding, Thomas R. Dugan, Patrick L. Holland, Debashis Adhikari, Daniel J. Mindiola. Edited by Thomas B. Rauchfuss. Inorganic Synthess, 2010, 35, 43-45. PDF
89. Iron 2,2,6,6-tetramethyl-3,5-bis-(2,6-diisopropylphenylimido)heptyl chloride (LFeCl)-Fe-tBu,iPr2). Karen P. Chiang, Patrick L. Holland, Debashis Adhikari, Daniel J. Mindiola. Edited by Thomas B. Rauchfuss. Inorganic Syntheses, 2010, 35, 41-43. PDF
88. Iron 2,4-bis-(2,6-diisopropylphenylimido)pentyl chloride (L(Me,iPr2)FeCl). Bryan D. Stubbert, Patrick L. Holland, Debashis Adhikari, Daniel J. Mindiola. Edited by Thomas B. Rauchfuss. Inorganic Syntheses, 2010, 35, 38-41. PDF
87. Scandium Trichloride Tris(Tetrahydrofuran) and beta-diketiminate-supported scandium chloride complexes. Paul G. Hayes, Warren E. Piers, Debashis Adhikari, and Daniel J. Mindiola. Edited by Thomas B. Rauchfuss. Inorganic Syntheses, 2010, 35, 20-24. PDF
86. beta-Diketiminate precursors (LH)-H-tBu,iPr2, and (LLi)-Li-tBu,iPr2(THF) (L-tBu, Li-iPr2 = 2,2,6,6-tetramethyl-3,5-bis-(2,6-diisopropylphenylimido)heptyl. Ryan E. Cowley, Karen P. Chiang, Patrick L. Holland, Debashis Adhikari, Francisco J. Zuno-Cruz, Gloria S. Cabrera, and Daniel J. Mindiola. Edited by Thomas B. Rauchfuss. Inorganic Syntheses, 2010, 35, 13-19. PDF
85. beta-Diketiminate precursors (LH)-H-Me,iPr2, [L-Me,Li-iPr2]x, and [(LK)-K-tBu,iPr2]x (L-Me,L-iPr2=2,4-bis-(2,6-diisopropylphenylimidi)pentyl;; L-tBu,L-tPr2 = 2,2,6,6-tetramethyl-3,5-bis-(2,6-diisopropylphenylimido)heptyl. Debashis Adhikari, Ba L. Tran, Francisco J. Zuno-Cruz, Gloria S. Cabrera, Daniel J. Mindiola, Karen P. Chiang, Ryan E. Cowley, Thomas R. Dugan, and Patrick L. Holland. Edited by Thomas B. Rauchfuss. Inorganic Syntheses, 2010, 35, 8-13. PDF
84. Complexes of bulky beta-diketiminate ligands. D. J. Mindiola, Patrick L. Holland, and Timothy H. Warren. Edited by Thomas B. Rauchfuss. Inorganic Syntheses, 2010, 35, 1-4. PDF
2009
83. Facile Entry to 3d Late Transition Metal Boryl Complexes. Ba L. Tran, Debashis Adhikari, Hongjun Fan, Maren Pink, and Daniel J. Mindiola Dalton Trans. 2009, 39, 358-360. Invited manuscript for the Theme Issue: New Talent; Inspiration for the Future. PDF
82. Nacnac...Are You Still There? The Evolution of β-Diketiminate Complexes of Nickel. Daniel J. Mindiola, Angew. Chem. Int. Ed. (Invited "Highlights" article), 2009, 48, 6198-6200. PDF
81. Phosphinidene Group-Transfer with a Phospha-Wittig Reagent: A New Entry to Transition Metal Phosphorus Multiple Bonds. Uriah J. Kilgore, Hongjun Fan, Maren Pink, Eugenijus Urnezius, John D. Protasiewicz and Daniel J. Mindiola, Chem. Commun. 2009, 4521-4523. PDF
80. A Tribute to Frederick Nye Tebbe. Lewis Acid Stabilized Alkylidynes, Alkylidenes, and Imides of 3d Early Transition Metals, Jennifer Scott and Daniel J. Mindiola, Dalton Trans. (Invited "Perspective" article and front cover of issue), 2009, 8463-8472. PDF
79. Zwitterionic and Cationic Titanium and Vanadium Complexes Having Terminal M-C Multiply Bonded Ligands. The Role of the β-Diketiminate Framework in Formation of Charge Separated Species. Debashis Adhikari, Falguni Basuli, Justin H. Orlando, Alison R. Fout, John C. Huffman, and Daniel J. Mindiola, Organometallics 2009, 28, 4115-4125. PDF
78. Catalytic Hydrosilylation of the Carbonyl Functionality via a Transient Nickel Hydride Complex. Ba L. Tran, Maren Pink, Daniel J. Mindiola, Organometallics 2009, 28, 2234-2243. PDF
77. Tellus in, Tellus out: The Chemistry of the Vanadium Bis(telluride) Functionality. Uriah J. Kilgore, Jonathan A. Karty, Maren Pink, Xinfeng Gao, and Daniel J. Mindiola, Angew. Chem. Int. Ed. 2009, 48, 2394-2397. PDF
76. Mild Protocol to Prepare Stable Nickel Complexes Having Primary and Secondary Silyl Ligands. Debashis Adhikari, Maren Pink, and Daniel J. Mindiola, Organometallics 2009, 28, 2072-2077. PDF
75.* A Transient V(III) Neopentylidene Complex. Redox Chemistry and Reactivity of the V=CHtBu Functionality. Uriah J. Kilgore, Caitlin A. Sengelaub, Hongjun Fan, John Tomaszewski, Maren Pink, Jonathan A. Karty, Mu-Hyun Baik, and Daniel J. Mindiola, Organometallics 2009, 28, 843-852. PDF
74.* Dehydrofluorination of Fluorohydrocarbons by Titanium Alkylidynes via Sequential C-H/C-F Bond Activation Reactions. A Synthetic, Structural, and Mechanistic Study of 1,2-CH Bond Addition and β-Fluoride Elimination. Alison R. Fout, Jennifer Scott, Deanna L. Miller, Brad C. Bailey, John C. Huffman, Maren Pink, and Daniel J. Mindiola, Organometallics 2009, 28, 331-347. PDF
2008
73. Lewis Acid Stabilized Methylidene and Oxoscandium Complexes. Jennifer Scott, Hongjun Fan, Benjamin F. Wicker, Alison R. Fout, Mu-Hyun Baik, and Daniel J. Mindiola, J. Am. Chem. Soc. 2008, 130, 14438-14439. PDF
72.* Understanding and Predicting Distorted T- vs. Y-Geometries for Neutral Chromous Complexes Supported by a Sterically Encumbering β-Diketiminate Ligand. Hongjun Fan, Debashis Adhikari, Anas A. Saleh, Rodney L. Clark, Francisco J. Zuno-Cruz, Gloria Sanchez Cabrera, John C. Huffman, Maren Pink, Daniel J. Mindiola, and Mu-Hyun Baik, J. Am. Chem. Soc. 2008, 130, 17351-17361. PDF
71. Evidence for the Existence of a Terminal Imidoscandium Compound. Intermolecular C-H Activation and Complexation Reactions with the Transient Sc=NAr Ligand. Jennifer Scott, Falguni Basuli, Alison R. Fout, John C. Huffman, and Daniel J. Mindiola, Angew. Chem. Int. 2008, 47, 8502-8505. PDF
70. Carboamination Reactions Using Titanium Pre-catalysts. A Catalytic Prospect to Preparing Conjugated C-N/C-C Frameworks. Daniel J. Mindiola, Comments on Inorg. Chem., Invited Article. 2008, 29, 73-92. website
69. P=N Bond Formation Via Incomplete N-Atom Transfer from a Ferrous Amide Precursor. Debashis Adhikari, Falguni Basuli, Hongjun Fan, John C. Huffman, and Daniel J. Mindiola, Inorg. Chem. 2008, 47, 4439-4441. PDF
68. Early-Transition Metal Hydrazidos: Masked Metallanitrenes from N-N Bond Scission. Daniel J. Mindiola, Angew. Chem. Int. Ed. (Invited "Highlights" article) 2008, 47, 1557-1559. PDF
67. Structural, Spectroscopic and Theoretical Elucidation of a Redox Active Pincer-Type Ancillary Applied in Catalysis. Debashis Adhikari, Susanne Mossin, Falguni Basuli, John C. Huffman, Robert K. Szilagyi, Karsten Meyer, and Daniel J. Mindiola, J. Am. Chem. Soc. 2008, 130, 3676-3682. PDF
66.* A Transient VIII Alkylidene Complex. Oxidation Chemistry Including the Activation of N2 to Afford a Highly Porous Honeycomb-Like Arrangement. Uriah J. Kilgore, Caitlin A. Sengelaub, Maren Pink, Alison R. Fout, and Daniel J. Mindiola, Angew. Chem. Int. 2008, 47, 3769-3772. PDF
65. A Dinuclear Ni(I) System Having a Diradical Ni2N2 Diamond Core Resting State. Synthetic, Structural, Spectroscopic Elucidation, and Reductive Bond Splitting Reactions. Debashis Adhikari, Susanne Mossin, Falguni Basuli, Benjamin R. Dible, Mircea Chipara, Hongjun Fan, John C. Huffman, Mu-Hyun Baik, Karsten Meyer, and Daniel J. Mindiola, Inorg. Chem. 2008, 47, 10479-10490. PDF
Assistant Professor
2007
64. Structural Elucidation of a Nickel Boryl Complex. A Recyclable Borylation Ni(II) Reagent of Bromobenzene. Debashis Adhikari, John C. Huffman, and Daniel J. Mindiola, Chem. Commun. 2007, 4489-4491. PDF
63. An Alkylidyne Analogue of Tebbe's Reagent. Trapping Reactions of a Titanium Neopentylidyne by Incomplete and Complete 1,2-Additions. Brad C. Bailey, Alison R. Fout, Hongjun Fan, John Tomaszewski, John C. Huffman, and Daniel J. Mindiola, Angew. Chem. Int. Ed. 2007, 46, 8246-8249. PDF
62. Cyclic Homogeneous Denitrogenation of N-Heterocycles Applying a Titanium Reagent. Alison R. Fout, Brad C. Bailey, John Tomaszewski, and Daniel J. Mindiola, J. Am. Chem. Soc. 2007, 129, 12640-12641. PDF. Editors' choice in Science Magazine. PDF
61. Niobium Bis-Alkylidene Complexes Prepared by a Multi-Electron Redox Process. Uriah J. Kilgore, John Tomaszewski, Hongjun Fan, John C. Huffman, and Daniel J. Mindiola, Organometallics 2007, 26, 6132-6138. PDF
60. The Progression of Synthetic Strategies to Assemble Titanium Complexes Bearing the Terminal Imide Group. Alison R. Fout, Uriah J. Kilgore, and Daniel J. Mindiola, Invited Concepts Article, Chem. Eur. J. 2007, 13, 9428-9440. PDF
59. Addition of Ammonia, Water, and Dihydrogen Across a Single Pd-Pd Bond. Claudia M. Fafard, Debashis Adhikari, Bruce M. Foxman, Daniel J. Mindiola, and Oleg. V. Ozerov, J. Am. Chem. Soc. 2007, 129, 10318-10319. PDF
58. Intermolecular C-H Bond Activation Reactions Promoted by Transient Titanium Alkylidynes. Synthesis, Reactivity, Kinetic, and Theoretical Studies of the Ti≡C Linkage. Brad C. Bailey, Hongjun Fan, John C. Huffman, Mu-Hyun Baik, and Daniel J. Mindiola, J. Am. Chem. Soc. 2007, 129, 8781-8793. PDF
57.* Silver(I) and Thallium(I) Complexes of a PNP Ligand and Their Utility as PNP Transfer Reagents. Jessica C. DeMott, Falguni Basuli, Uriah J. Kilgore, Bruce M. Foxman, John C. Huffman, Oleg V. Ozerov, and Daniel J. Mindiola, Inorg. Chem. 2007, 46, 6271-6276. PDF
56. Snapshots of an Alkylidyne for Nitride Triple Bond Metathesis. Brad C. Bailey, Alison R. Fout, Hongjun Fan, John C. Huffman, J. Brannon Gary, Marc J. A. Johnson, and Daniel J. Mindiola, J. Am. Chem. Soc. 2007, 129, 2234-2235. PDF
55. Intermolecular Activation of C-X (X = H, O, F) Bonds by a Ti≡CtBu Linkage. Brad C. Bailey, John C. Huffman, and Daniel J. Mindiola, J. Am. Chem. Soc. 2007, 129, 5302-5303. PDF
54. Organometallic Consequences of a Redox Reaction. Terminal Trimethylsilylmethylidene Titanium Complexes Prepared by a One-Electron Oxidation Step. Falguni Basuli, Debashis Adhikari, John C. Huffman, and Daniel J. Mindiola, Invited paper for the volume entitled 'One-Electron Reactivity in Organometallic Chemistry'. J. Organomet. Chem. 2007, 692, 3115-3120. Manuscript selected for front art cover. PDF
53. Reductive Cleavage on the NCCCN β-Diketiminate Backbone. A Direct Approach to Azabutadienyl and Alkylidene-Anilide Scaffolds. Invited paper for the issue Inorganic Chemistry - The Next Generation. F. Basuli, J. C. Huffman, D. J. Mindiola, Inorg. Chim. Acta. 2007, 360, 246-254. PDF
2006
52. Activation of Atmospheric Nitrogen and Azobenzene N=N Bond Cleavage by a Transient Nb(III) Complex. Uriah J. Kilgore, Xiaofang Yang, John C. Huffman, and Daniel J. Mindiola, Inorg. Chem. 2006, 45, 10712-10721. PDF
Addition for the above manuscript: PDF
51. Neutral and Zwitterionic Low-Coordinate Titanium Complexes Bearing the Terminal Phosphinidene Functionality. Structural, Spectroscopic, Theoretical, and Catalytic Studies Addressing the Ti-P Multiple Bond. Guangyu Zhao, Falguni Basuli, Uriah J. Kilgore, Hongjun Fan, Halikhedkar Aneetha, John C. Huffman, Gang Wu, and Daniel J. Mindiola, J. Am. Chem. Soc. 2006, 128, 13575-13585. PDF
50. Oxidatively-Induced α-Hydrogen Abstraction. A Mild Protocol to Generate Terminal Titanium Alkylidenes Containing a β-Hydrogen. Brad C. Bailey, Falguni Basuli, John C. Huffman, and Daniel J. Mindiola, Organometallics 2006, 25, 3963-3968. PDF
49. Oxidatively Induced Abstraction Reactions. A Synthetic Approach to Low-Coordinate, Reactive, Early-Transition Metal Complexes Containing Metal-Ligand Multiple Bonds. Daniel J. Mindiola, Invited Microreview, Acc. Chem. Res. 2006, 39, 813-821. PDF
48. What a Difference One Electron Makes! Generating Low-Coordinate Ti-C and V-C Multiply Bonded Frameworks Through One-Electron Oxidatively-Induced α-Hydrogen Abstractions. Daniel J. Mindiola, Brad C. Bailey, and Falguni Basuli, Invited Microreview, Eur. J. Inorg. Chem. 2006, 3135-3146. PDF
47. Room Temperature Ring-Opening Metathesis of Pyridines by a Transient Ti≡C Linkage. Brad C. Bailey, Hongjun Fan, John C. Huffman, Mu-Hyun Baik, and Daniel J. Mindiola, J. Am. Chem. Soc. 2006, 128, 6798-6799. PDF
Correction for the above manuscript: PDF
46. Terminal Titanium(IV) (Trimethylsilyl)imides Prepared by Oxidatively Induced Trimethylsilyl Abstraction. Brad C. Bailey, Falguni Basuli, John C. Huffman, and Daniel J. Mindiola, Organometallics 2006, 25, 2725-2728. PDF
45. Ti(NMe2)4 and [HNMe2Ph][B(C6F5)4]: A Convenient Blend for Effective Catalytic Carboamination of Alkynes. H. Aneetha, F. Basuli, J. Bollinger, J. C. Huffman, and D. J. Mindiola, Organometallics 2006, 25, 2402-2404. PDF
44. Tl(I), Fe(II) and Co(II) Complexes Supported by a Monoanionic N,N,N'-Heteroscorpionate Ligand Bis(3,5-di-tertbutylpyrazol-1-yl)-1-CH2NAr, Ar = 2,6-iPr2C6H3). D. Adhikari, G. Zhao, F. Basuli, J. Tomaszewski, J. C. Huffman, D. J. Mindiola, Inorg. Chem. 2006, 45, 1604-1610. PDF
43. A Co2N2 Diamond Core Resting State of Cobalt(I): A Three-Coordinate Co(I) Synthon Invoking an Unusual Pincer-Type Rearrangement. A. R. Fout, F. Basuli, H. Fan, J. Tomaszewski, J. C. Huffman, M.-H. Baik, D. J. Mindiola, Angew. Chem. Int. Ed. 2006, 45, 3291-3295. PDF
42. Aryl Isocyanate, Carbodiimide, and Isocyanide Derived Prepared from Carbon Dioxide. A Metathetical Group-Transfer Tale Involving a Titanium-Imide Zwitterion. U. J. Kilgore, F. Basuli, J. C. Huffman, D. J. Mindiola. Inorg. Chem. 2006, 45, 487-489. PDF
2005
41. A Fluorobenzene Adduct of Ti(IV), and Catalytic Carboamination to Prepare α,β-Unstaturated Imines and Triaryl Substituted Quinolines. F. Basuli, H. Annetha, J. C. Huffman, D. J. Mindiola, J. Am. Chem. Soc. 2005, 127, 17992-17993. PDF
40.* Titanium Complexes Supported by a Sterically Encumbering N-Anchored Tris-Aryl Phenoxide Ligand. S. A. Cortes, M. A. Muñoz Hernández, I. Castro-Rodriguez, K. Meyer, A. R. Fout, D. A. Miller, J. C. Huffman, D. J. Mindiola, Inorg. Chem. Commun. 2005, 8, 902-906. PDF
39. Intermolecular C-H Bond Activation Promoted by a Titanium Alkylidyne. B. C. Bailey, H. Fan, E. W. Baum, J. C. Huffman, M.-H. Baik, D. J. Mindiola, J. Am. Chem. Soc. 2005, 127, 16016-16017. PDF
38.* Latent Low-Coordinate Titanium Imides Supported by a Sterically Encumbering Beta-Diketiminate Ligand. F. Basuli, R. L. Clark, B. C. Bailey, D. Brown, J. C. Huffman, D. J. Mindiola, Chem. Commun. 2005, 2250-2252. PDF
37. Remarkably Stable Titanium Complexes Having Terminal Alkylidene, Phosphinidene, and Imide Functionalities. B. C. Bailey, J. C. Huffman, D. J. Mindiola, W. Weng, O. V. Ozerov, Organometallics 2005, 2, 1390-1393. PDF
36. Intramolecular C-H Activation Reactions Derived From a Terminal Titanium Neopentylidene Functionality. Redox Controlled 1,2-Addition and α-Hydrogen Abstraction Reactions. F. Basuli, B. C. Bailey, J. C. Huffman, D. J. Mindiola, Organometallics 2005, 24, 3321-3334. PDF
35. Four-Coordinate Titanium Alkylidene Complexes: Synthesis, Reactivity, and Kinetic Studies Involving the Terminal Neopentylidene Functionality. F. Basuli, B. C. Bailey, L. A. Watson, J. Tomaszewski, J. C. Huffman, D. J. Mindiola, Organometallics 2005, 24, 1886-1906. PDF
Addition/Correction for the above manuscript: PDF
2004
34.* Terminal Zirconium Imides Prepared by Reductive C-N Bond Cleavage. F. Basuli, U. J. Kilgore, J. Tomaszewski, D. Brown, J. C. Huffman, D. J. Mindiola, Organometallics 2004, 23, 6166-6175. PDF
33. Four-Coordinate Vanadium-Neopentylidyne Complexes and Intramolecular Wittig Reactions to Generate Azametallacyclohexatrienes. F. Basuli, B. C. Bailey, D. Brown, J. Tomaszewski, J. C. Huffman, M.-H. Baik, D. J. Mindiola, J. Am. Chem. Soc. 2004, 126, 10506-10507. PDF
32. Terminal and Four-Coordinate Vanadium(IV) Phosphinidene Complexes. A Pseudo Jahn-Teller Effect of Second Order Stabilizing the V-P Multiple Bond. F. Basuli, B. C. Bailey, J. C. Huffman, Mu-H. Baik, D. J. Mindiola, J. Am. Chem. Soc. 2004, 126, 1924-1925. PDF
31.* Cationic and Neutral Four-Coordinate Alkylidene Complexes of Vanadium(IV) Containing Short V=C Bonds, F. Basuli, U. J. Kilgore, X. Hu, K. Meyer, M. Pink, J. C. Huffman, D. J. Mindiola, Angew. Chem. Int. Ed. 2004, 43, 3156-3158. PDF
2003
30. Phosphaazaallene and Phosphinylimide Complexes Stemming From a Terminal and Four-Coordinate Titanium Phosphinidene, F. Basuli, L. A. Watson, J. C. Huffman, D. J. Mindiola, Dalton Trans. 2003, 4228-4230. PDF
29. Reactivity at the β-Dketiminate Ligand Nacnac- on Ti(IV) (Nacnac- = [Ar]N(CH3)CHC(CH3)N[Ar], Ar = 2,6-[CH(CH3)2]2C6H3. Diimine-alkoxo and Bis-Anilido Ligands Stemming from the Nacnac- Skeleton, F. Basuli, J. C. Huffman, D. J. Mindiola, Inorg. Chem. 2003, 42, 8003-8010. PDF
28. Carbon-Oxygen Bond Cleavage Promoted by a Scandium-Hydride Complex, F. Basuli, J. Tomaszewski, J. C. Huffman, D. J. Mindiola, Organometallics 2003, 22, 4705-4714. PDF
27. Four-Coordinate Phosphinidene Complexes of Titanium Prepared by α-Hydrogen Migration: Phospha-Staudinger and Phosphaalkene Insertion Reactions, F. Basuli, J. Tomaszewski, J. C. Huffman, D. J. Mindiola, J. Am. Chem. Soc. 2003, 125, 10170-10171. PDF
26. Snapshots of an Oxidatively Induced α-Hydrogen Abstraction Reaction to Prepare a Four-Coordinate Titanium Imide, F. Basuli, B. C. Bailey, J. C. Huffman, D. J. Mindiola, Chem. Commun. 2003, 1554-1555. PDF
25. A Terminal and Four-Coordinate Titanium Alkylidene Prepared by Oxidatively Induced α-Hydrogen Abstraction, F. Basuli, B. C. Bailey, J. Tomaszewski, J. C. Huffman, D. J. Mindiola, J. Am. Chem. Soc. 2003, 125, 6052-6053. PDF
Post-doctoral
24. Carbon–Hydrogen Bond Activation, C–N Bond Coupling, and Cycloaddition Reactivity of a Three-Coordinate Nickel Complex Featuring a Terminal Imido Ligand. Daniel J. Mindiola, Rory Waterman, Vlad M. Iluc, Thomas R. Cundari, and Gregory L. Hillhouse,Inorg. Chem. 2014, 53, 13227-13238. PDF
23. Synthesis, Structure and Reactivity of Platinum Compounds Featuring Terminal Amido and Phosphido Ligands. Rory Waterman, Daniel J. Mindiola, Christopher Clough, and Gregory L. Hillhouse, Inorg. Chimica Acta (special issue in honor of Prof. T. Don Tilley) 2014, 422, 57-64. PDF
22. Functionalization of Complexed N2O in Bis(pentamethylcyclopentadienyl) Systems of Zirconium and Titanium. Daniel J. Mindiola, Lori A. Watson, Karsten Meyer, and Gregory L. Hillhouse, Organometallics 2014, 33, 2760-2769. PDF
21. Preparation of Stable Alkyl Complexes of Ni(I) and Their 1-Electron Oxidation to Ni(II) Complex Cations. Kristina D. Kitiachvili, Daniel J. Mindiola, Gregory L. Hillhouse, J. Am. Chem. Soc. 2004, 126, 10554-10555. PDF
20. Synthesis of 1,2-Bis(di-tert-butylphosphino)ethane (dtbpe) Complexes of Nickel: Radical Coupling and Reduction Reactions Promoted by the Nickel(I) Dimer [(dtbpe)NiCl]2, Daniel J. Mindiola, Rory Melenkivitz, David M. Jenkins, Gregory L. Hillhouse, Special issue dedicated to Prof. R. R. Schrock, Inorg. Chim. Acta. 2003, 345, 299-308. PDF
19. Synthesis, Structure, and Reactions of a Three-Coordinate Nickel-Carbene Complex, {1,2-Bis(di-tert-butylphosphino)ethane}Ni=CPh2, Daniel J. Mindiola and Gregory L. Hillhouse, J. Am. Chem. Soc. 2002, 124, 9976-9977. PDF
18. Isocyanate and Carbodiimide Synthesis by Nitrene-Group-Transfer from a Nickel Imido Complex, Daniel J. Mindiola and Gregory L. Hillhouse, Chem. Commun. 2002, 1840-1841. PDF
17. Monomeric Phosphido and Phosphinidene Complexes of Nickel, R. Melenkivitz, Daniel J. Mindiola and Gregory L. Hillhouse, J. Am. Chem. Soc. 2002, 124, 3846-3847. PDF
16. Terminal Amido and Imido Complexes of Three-Coordinate Nickel, Daniel J. Mindiola and Gregory L. Hillhouse, J. Am. Chem. Soc. 2001, 123, 4623-4624. PDF
Graduate
15. Niobaziridine Hydrides. Joshua S. Figueroa, Nicholas A. Piro, Daniel J. Mindiola, Michael G. Fickes, Christopher C. Cummins (Prof. Dietmar Seyferth Festschrift) Organometallics 2010, 29, 5215-5229. PDF
14. Radical Scission of Symmetrical 1,4-Dicarbonyl Compounds: C-C Bond Cleavage with Ti(IV) Enolate Formation and Related Reactions, Theodore Agapie, Paula L. Diaconescu, Daniel J. Mindiola, Christopher C. Cummins, Organometallics 2002, 21, 1329-1340. PDF
13. Probing the Niobium Metallaaziridine Functionality, Daniel J. Mindiola, Christopher C. Cummins, Organometallics 2001, 20, 3626-3628. PDF
12. Bimetallic μ-Cyanoimide Complexes Prepared by NCN Group Transfer, Daniel J. Mindiola, Yi-C. Tsai, Q. Chen, R. Hara, Thomas A. Baker, Karsten Meyer, Christopher C. Cummins, Chem. Commun. 2001, 125-126. PDF
11. Uranium Hexakisamido Complexes, Karsten Meyer, Daniel J. Mindiola, Tom A. Baker, William M. Davis, Christopher C. Cummins, Angew. Chem. Int. Ed., Engl. 2000, 39, 3063-3066. PDF
10. Arene-Bridged Diuranium Complexes: Inverted Sandwiches Supported by δ Backbonding, Paula L. Diaconescu, Polly L. Arnold, Thomas A. Baker, Daniel J. Mindiola, Christopher C. Cummins, J. Am. Chem. Soc. 2000, 122, 6108-6109. PDF
9. Dinitrogen Cleavage Stemming from a Heterodinuclear Niobium/Molybdenum N2 Complex: New Nitridoniobium Systems Including a Niobazene Cyclic Trimer, Daniel J. Mindiola, Karsten Meyer, John P.-F. Cherry, Thomas A. Baker, Christopher C. Cummins, Organometallics, 2000, 19, 1622-1624. PDF
8. A Cyclometallated Resting State for a Reactive Molybdenum Amide: Favorable Consequences of beta-Hydrogen Elimination Including Reductive Cleavage, Coupling and Complexation, Yi-C. Tsai, Marc J. A. Johnson, Daniel J. Mindiola, W. T. Klooster, Thomas F. Koetzle, Christopher C. Cummins, J. Am. Chem. Soc. 1999, 121, 10426-10427. PDF
7. Redox-Catalyzed Binding of Dinitrogen by Molybdenum N-tert-Hydrocarbylanilide Complexes: Implications for Dinitrogen Functionalization and Reductive Cleavage, Jonas C. Peters, John P. -F. Cherry, Chris Thomas, Luis Baraldo, Daniel J. Mindiola, Christopher C. Cummins, J. Am. Chem. Soc. 1999, 121, 10053-10067. PDF
6. A Nucleophilic Chromium(V) Dioxo Radical Anion, Aaron L. Odom, Daniel J. Mindiola, Christopher C. Cummins, Inorg. Chem. 1999, 38, 3290-3295. PDF
5. Deprotonated 2,3:5,6-Dibenzo-7-azabicyclo[2.2.1]hepta-2,5-diene as a Nitrido Nitrogen Source via Anthracene Elimination, Daniel J. Mindiola, Christopher.C. Cummins, Angew. Chem. Int. Ed., Engl. 1998, 37, 945-948. PDF
Undergraduate
4. Reactions of DNA Purines with Rhodium Formamidinate Compounds that Display Antitumor Behavior, K. V. Catalan, J. S. Hess, M. M. Maloney, D. J. Mindiola, D. L. Ward, K. R. Dunbar, Inorg. Chem. 1999, 38, 3904-3913. PDF
3. A Quadruply-Bonded Dirhenium Complex Bridged by Two N1/N6 Adenate Ligands, M. E. Prater, D. J. Mindiola, X. Ouyang, K. R. Dunbar, Inorg. Chem. Commun. 1998, 1, 475-477. PDF
2. A Novel Dirhodium Compound with Neutral, Bridging 9-Ethyladenine Ligands, K. V. Catalan, D. J. Mindiola, D. L. Ward, and K. R. Dunbar, Inorg. Chem. 1997, 36, 2458-2460. PDF
1. Acetyltransfer Precedes Uridylyltransfer in the Formation of UDP-N-acetylglucosamine in Separable Active Sites of the Bifunctional GlmU Protein of Escherichia coli, E. D. Brown, A. M. Gehring, J. L. Watson J., D. J. Mindiola, C. T. Walsh, Biochemistry 1996, 35, 579-585. PDF