
The alkylidene phenyl complex depicted is the product arising from C-H activation of benzene via a transient titanium alkylidyne. This complex can undergo α-H abstraction at high temperatures to regenerate the Ti≡C linkage! For some more information about this species: Bailey, B. C., etal. J. Am. Chem. Soc. 2005, 127, 16016-16017.